C₃₃H₄₅NO₇Si

Base Information

Chemical Name:C₃₃H₄₅NO₇Si
CAS No.:1393603-62-7
Molecular Formula:C₃₃H₄₅NO₇Si
Molecular Weight:595.808
Hs Code.:

C<sub>33</sub>H<sub>45</sub>NO<sub>7</sub>Si

Synonyms:C₃₃H₄₅NO₇Si

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Chemical Property of C₃₃H₄₅NO₇Si

Chemical Property:

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Technology Process of C₃₃H₄₅NO₇Si

There total 15 articles about C₃₃H₄₅NO₇Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 60032-63-5
4-hydroxy-3-iodo-benzaldehyde

: 1393603-62-7
C₃₃H₄₅NO₇Si

: 1393603-63-8
C₃₃H₄₅NO₇Si

Guidance literature:: Multi-step reaction with 4 steps

1.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 16 h / 20 °C / Cooling with ice

2.1: potassium acetate; palladium diacetate / N,N-dimethyl-formamide / 60 °C / Inert atmosphere

3.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; cesium fluoride / 1,2-dimethoxyethane / 18 h / 95 °C / Inert atmosphere

4.1: 18-crown-6 ether; potassium hexamethylsilazane / tetrahydrofuran; toluene / 0.17 h / -78 °C / Inert atmosphere

4.2: -78 - 0 °C / Inert atmosphere

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; 18-crown-6 ether; potassium acetate; palladium diacetate; potassium hexamethylsilazane; N-ethyl-N,N-diisopropylamine; cesium fluoride; In tetrahydrofuran; 1,2-dimethoxyethane; dichloromethane; N,N-dimethyl-formamide; toluene;
DOI:10.1039/c2ob25880c

Reference yield:

: 1393603-37-6
(4S,9aR)-hexahydro-4-(2-(2'-methoxymethoxy-5'-carboxaldehyphenyl)-4,5-dimethoxyphenyl)-1H-quinolizin-2(6H)-one

: 394657-61-5
(diphenoxy-phosphoryl)acetic acid 2-trimethylsilanyl-ethyl ester

: 1393603-62-7
C₃₃H₄₅NO₇Si

: 1393603-63-8
C₃₃H₄₅NO₇Si

Guidance literature:: (diphenoxy-phosphoryl)acetic acid 2-trimethylsilanyl-ethyl ester; With 18-crown-6 ether; potassium hexamethylsilazane; In tetrahydrofuran; toluene; at -78 ℃; for 0.166667h; Inert atmosphere;

(4S,9aR)-hexahydro-4-(2-(2'-methoxymethoxy-5'-carboxaldehyphenyl)-4,5-dimethoxyphenyl)-1H-quinolizin-2(6H)-one; In tetrahydrofuran; toluene; at -78 - 0 ℃; optical yield given as %de; Inert atmosphere;
DOI:10.1039/c2ob25880c

Reference yield:

: 1393603-29-6
C₁₃H₂₅NO₃

: 1393603-62-7
C₃₃H₄₅NO₇Si

: 1393603-63-8
C₃₃H₄₅NO₇Si

Guidance literature:: Multi-step reaction with 6 steps

1.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 2 h / 20 °C

2.1: sodium hydroxide / methanol / 16 h / 55 °C

3.1: trifluoroacetic acid / dichloromethane / 1 h / 0 °C

4.1: sodium hydroxide / tetrahydrofuran / 4 h / 0 - 20 °C

5.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; cesium fluoride / 1,2-dimethoxyethane / 18 h / 95 °C / Inert atmosphere

6.1: 18-crown-6 ether; potassium hexamethylsilazane / tetrahydrofuran; toluene / 0.17 h / -78 °C / Inert atmosphere

6.2: -78 - 0 °C / Inert atmosphere

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; 18-crown-6 ether; potassium hexamethylsilazane; sodium hydrogencarbonate; Dess-Martin periodane; cesium fluoride; trifluoroacetic acid; sodium hydroxide; In tetrahydrofuran; methanol; 1,2-dimethoxyethane; dichloromethane; toluene;
DOI:10.1039/c2ob25880c