[Pd(η2-naphthoquinone)(8-diphenylphosphanyl-2-methylquinoline)]

Base Information

• Chemical Name: [Pd(η2-naphthoquinone)(8-diphenylphosphanyl-2-methylquinoline)]
• CAS No.: 1083211-26-0
• Molecular Formula: C₃₂H₂₄NO₂PPd
• Molecular Weight: 591.942
• Mol file: 1083211-26-0.mol

Synonyms:[Pd(η2-naphthoquinone)(8-diphenylphosphanyl-2-methylquinoline)]

Chemical Property of [Pd(η2-naphthoquinone)(8-diphenylphosphanyl-2-methylquinoline)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pd(η2-naphthoquinone)(8-diphenylphosphanyl-2-methylquinoline)]

There total 2 articles about [Pd(η2-naphthoquinone)(8-diphenylphosphanyl-2-methylquinoline)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

tris(dibenzylideneacetone)dipalladium(0) chloroform complex (52522-40-4) + [1,4]naphthoquinone (130-15-4) + 2-methyl-8-(diphenylphosphino)quinoline (478548-99-1) → [Pd(η2-naphthoquinone)(8-diphenylphosphanyl-2-methylquinoline)] (1083211-26-0)

Guidance literature:

In acetone; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1016/j.jorganchem.2017.02.003

Reference yield:

[PdCl(8-diphenylphosphanyl-2-methylquinoline)(C(COOMe)C(COOMe)C(COOMe)C(Me)COOMe)] (858132-94-2) + [1,4]naphthoquinone (130-15-4) → [Pd(η2-naphthoquinone)(8-diphenylphosphanyl-2-methylquinoline)] (1083211-26-0)

Guidance literature:

With tributyl-phenylethynyl-stannane; In chloroform-d1; byproducts: (2Z,4Z)-PhC(MeO2CC=CCO2Me)2Me; concd. soln. of Sn compd. and olefin was added to soln. of Pd complex inCDCl3; reacted for 60 min; NMR monitoring;

DOI:10.1016/j.jorganchem.2008.07.028

Reference yield:

[Pd(η2-naphthoquinone)(8-diphenylphosphanyl-2-methylquinoline)] (1083211-26-0) + 2-propynyl chloride (624-65-7) → C25H21ClNPPd

Guidance literature:

In dichloromethane; for 0.333333h; regioselective reaction; Inert atmosphere;

DOI:10.1016/j.jorganchem.2017.02.003

upstream raw materials:

tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex

[1,4]naphthoquinone

2-methyl-8-(diphenylphosphino)quinoline

[PdCl(8-diphenylphosphanyl-2-methylquinoline)(C(COOMe)C(COOMe)C(COOMe)C(Me)COOMe)]