2-methoxy-2-(S)-phenyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-β-D-glucopyranoso)[1,2-e]-1,4-oxathiane

Base Information

Chemical Name:2-methoxy-2-(S)-phenyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-β-D-glucopyranoso)[1,2-e]-1,4-oxathiane
CAS No.:1197819-99-0
Molecular Formula:C₂₁H₂₆O₉S
Molecular Weight:454.498
Hs Code.:

Synonyms:2-methoxy-2-(S)-phenyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-β-D-glucopyranoso)[1,2-e]-1,4-oxathiane

Suppliers and Price of 2-methoxy-2-(S)-phenyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-β-D-glucopyranoso)[1,2-e]-1,4-oxathiane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2-methoxy-2-(S)-phenyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-β-D-glucopyranoso)[1,2-e]-1,4-oxathiane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2-methoxy-2-(S)-phenyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-β-D-glucopyranoso)[1,2-e]-1,4-oxathiane

There total 6 articles about 2-methoxy-2-(S)-phenyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-β-D-glucopyranoso)[1,2-e]-1,4-oxathiane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 1197819-98-9
2-methoxy-2-(S)-phenyl-(1,2-dideoxy-β-D-glucopyranoso)[1,2-e]-1,4-oxathiane

: 108-24-7
acetic anhydride

: 1197819-99-0
2-methoxy-2-(S)-phenyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-β-D-glucopyranoso)[1,2-e]-1,4-oxathiane

Guidance literature:: With pyridine; at 0 - 20 ℃; for 19h; Inert atmosphere;
DOI:10.1039/b913308a

Reference yield: 62.0%

: 1197820-01-1
2-methoxy-2-(S)-phenyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-β-D-glucopyranoso)[1,2-e]-1,4-oxathiane (R)-S-oxide

: 1197819-99-0
2-methoxy-2-(S)-phenyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-β-D-glucopyranoso)[1,2-e]-1,4-oxathiane

Guidance literature:: 2-methoxy-2-(S)-phenyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-β-D-glucopyranoso)[1,2-e]-1,4-oxathiane (R)-S-oxide; With 2,6-di-tert-butyl-4-methylpyridine; trifluoromethylsulfonic anhydride; In dichloromethane; at -60 ℃; for 0.0833333h; Molecular sieve; Inert atmosphere;

With diphenyl sulfide; In dichloromethane; at -60 ℃; for 0.666667h; Molecular sieve; Inert atmosphere;
DOI:10.1002/chem.201102861

Reference yield:

: 3254-12-4
2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranosyl acetophenone

: 1197819-99-0
2-methoxy-2-(S)-phenyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-β-D-glucopyranoso)[1,2-e]-1,4-oxathiane

Guidance literature:: Multi-step reaction with 3 steps

1: sodium methylate / methanol / Inert atmosphere

2: toluene-4-sulfonic acid / Inert atmosphere

3: pyridine / Inert atmosphere

With pyridine; sodium methylate; toluene-4-sulfonic acid; In methanol;
DOI:10.1002/chem.201101889