[(PCy₂(2-biphenyl))AuBr]

Base Information

Chemical Name:[(PCy₂(2-biphenyl))AuBr]
CAS No.:925253-63-0
Molecular Formula:C₂₄H₃₁AuBrP
Molecular Weight:627.354
Hs Code.:

Synonyms:[(PCy₂(2-biphenyl))AuBr]

Suppliers and Price of [(PCy₂(2-biphenyl))AuBr]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [(PCy₂(2-biphenyl))AuBr]

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [(PCy₂(2-biphenyl))AuBr]

There total 1 articles about [(PCy₂(2-biphenyl))AuBr] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 854045-92-4
chloro([1,1'-biphenyl]-2-yldicyclohexylphosphine)gold(I)

: 7558-02-3,7758-02-3
potassium bromide

: 925253-63-0
[(PCy₂(2-biphenyl))AuBr]

Guidance literature:: In dichloromethane; water; an aq. soln. of KBr added to a CH2Cl2 soln. of Au complex, stirred for 4h; the aq. layer washed with CH2Cl2, the org. layers combined, washed (H2O), dried (MgSO4), filtered, evapd. (vac.), pentane added, the solid collected, dried; elem. anal.;
DOI:10.1021/om700517q

Reference yield: 84.0%

: 925253-63-0
[(PCy₂(2-biphenyl))AuBr]

: 98-80-6
phenylboronic acid

: 925253-77-6
([(PCy₂)(2-biphenyl)]Au(phenyl))

Guidance literature:: With Cs₂CO₃; In isopropyl alcohol; Cs-compd. and B-compd. suspended in isopropyl alcohol, Au-compd. added, stirred at 50°C for 24 h, cooled; evaporated in vac., extracted into benzene, filtered through celite, concentrated, pentane added, evaporated, washed with pentane, dried, extracted into benzene, filtered, concentrated, pentane diffused, washed with cold methanol and pentane, dried;
DOI:10.1002/anie.200603350