Technology Process of C35H61NO5
There total 21 articles about C35H61NO5 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
[Ir(cod)(SIMes)(Pyr)]+PF6-; hydrogen;
In
dichloromethane;
at 20 ℃;
for 18h;
under 67506.8 Torr;
diastereoselective reaction;
Autoclave;
DOI:10.1002/anie.201303776
- Guidance literature:
-
Multi-step reaction with 7 steps
1.1: triphenylphosphine; di-isopropyl azodicarboxylate / tetrahydrofuran / 2 h / 0 °C / Inert atmosphere
2.1: water; sodium hydroxide / methanol / 1 h / Reflux
3.1: methyllithium / tetrahydrofuran / 0.67 h / -20 - 20 °C / Inert atmosphere
3.2: 1 h / 40 °C / Inert atmosphere
3.3: 0.25 h / 0 °C / Inert atmosphere
4.1: tert.-butyl lithium / diethyl ether; pentane / 0.17 h / -78 °C / Inert atmosphere
4.2: 2 h / -78 - 20 °C / Inert atmosphere
4.3: 2 h / 20 °C / Darkness
5.1: pyridine / dichloromethane / 1 h / 0 °C / Inert atmosphere
6.1: tetra-N-butylammonium tribromide / methanol / 4 h / 20 °C / Inert atmosphere
7.1: hydrogen; [Ir(cod)(SIMes)(Pyr)]+PF6- / dichloromethane / 18 h / 20 °C / 67506.8 Torr / Autoclave
With
pyridine; di-isopropyl azodicarboxylate; [Ir(cod)(SIMes)(Pyr)]+PF6-; water; methyllithium; hydrogen; tert.-butyl lithium; tetra-N-butylammonium tribromide; triphenylphosphine; sodium hydroxide;
In
tetrahydrofuran; methanol; diethyl ether; dichloromethane; pentane;
DOI:10.1002/anie.201303776
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: triphenylphosphine; iodine; 1H-imidazole / acetonitrile; diethyl ether / 0.5 h / 0 °C / Inert atmosphere
2.1: tert.-butyl lithium / diethyl ether; pentane / 0.17 h / -78 °C / Inert atmosphere
2.2: 2 h / -78 - 20 °C / Inert atmosphere
2.3: 2 h / 20 °C / Darkness
3.1: pyridine / dichloromethane / 1 h / 0 °C / Inert atmosphere
4.1: tetra-N-butylammonium tribromide / methanol / 4 h / 20 °C / Inert atmosphere
5.1: hydrogen; [Ir(cod)(SIMes)(Pyr)]+PF6- / dichloromethane / 18 h / 20 °C / 67506.8 Torr / Autoclave
With
pyridine; 1H-imidazole; [Ir(cod)(SIMes)(Pyr)]+PF6-; hydrogen; iodine; tert.-butyl lithium; tetra-N-butylammonium tribromide; triphenylphosphine;
In
methanol; diethyl ether; dichloromethane; acetonitrile; pentane;
DOI:10.1002/anie.201303776