(Z)-ethyl 2-(((2R,3S,5R,6S)-5-(benzyloxy)-6-(benzyloxymethyl)-3-(tert-butyldimethylsilyloxy)-6-methyltetrahydro-2H-pyran-2-yl)methylene)-3-methylbutanoate

Base Information

Chemical Name:(Z)-ethyl 2-(((2R,3S,5R,6S)-5-(benzyloxy)-6-(benzyloxymethyl)-3-(tert-butyldimethylsilyloxy)-6-methyltetrahydro-2H-pyran-2-yl)methylene)-3-methylbutanoate
CAS No.:1224893-06-4
Molecular Formula:C₃₅H₅₂O₆Si
Molecular Weight:596.88
Hs Code.:

(Z)-ethyl 2-(((2R,3S,5R,6S)-5-(benzyloxy)-6-(benzyloxymethyl)-3-(tert-butyldimethylsilyloxy)-6-methyltetrahydro-2H-pyran-2-yl)methylene)-3-methylbutanoate

Synonyms:(Z)-ethyl 2-(((2R,3S,5R,6S)-5-(benzyloxy)-6-(benzyloxymethyl)-3-(tert-butyldimethylsilyloxy)-6-methyltetrahydro-2H-pyran-2-yl)methylene)-3-methylbutanoate

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Chemical Property of (Z)-ethyl 2-(((2R,3S,5R,6S)-5-(benzyloxy)-6-(benzyloxymethyl)-3-(tert-butyldimethylsilyloxy)-6-methyltetrahydro-2H-pyran-2-yl)methylene)-3-methylbutanoate

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Technology Process of (Z)-ethyl 2-(((2R,3S,5R,6S)-5-(benzyloxy)-6-(benzyloxymethyl)-3-(tert-butyldimethylsilyloxy)-6-methyltetrahydro-2H-pyran-2-yl)methylene)-3-methylbutanoate

There total 1 articles about (Z)-ethyl 2-(((2R,3S,5R,6S)-5-(benzyloxy)-6-(benzyloxymethyl)-3-(tert-butyldimethylsilyloxy)-6-methyltetrahydro-2H-pyran-2-yl)methylene)-3-methylbutanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

: 148515-21-3,35051-50-4
ethyl 2-(diethoxyphosphoryl)-3-methylbutyrate

: 1192598-40-5
C₂₈H₄₀O₅Si

: 1224893-06-4
(Z)-ethyl 2-(((2R,3S,5R,6S)-5-(benzyloxy)-6-(benzyloxymethyl)-3-(tert-butyldimethylsilyloxy)-6-methyltetrahydro-2H-pyran-2-yl)methylene)-3-methylbutanoate

Guidance literature:: ethyl 2-(diethoxyphosphoryl)-3-methylbutyrate; With sodium hydride; In tetrahydrofuran; at 0 ℃; for 0.166667h; Inert atmosphere;

C₂₈H₄₀O₅Si; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1021/ja101673v

Reference yield:

: 1224893-06-4
(Z)-ethyl 2-(((2R,3S,5R,6S)-5-(benzyloxy)-6-(benzyloxymethyl)-3-(tert-butyldimethylsilyloxy)-6-methyltetrahydro-2H-pyran-2-yl)methylene)-3-methylbutanoate

: C₃₃H₅₀O₅Si

Guidance literature:: (Z)-ethyl 2-(((2R,3S,5R,6S)-5-(benzyloxy)-6-(benzyloxymethyl)-3-(tert-butyldimethylsilyloxy)-6-methyltetrahydro-2H-pyran-2-yl)methylene)-3-methylbutanoate; With diisobutylaluminium hydride; In dichloromethane; toluene; at -78 ℃; for 1h; Inert atmosphere;

With water; silica gel; In dichloromethane; isopropyl alcohol; toluene; at -78 - 24 ℃; Inert atmosphere; Celite;
DOI:10.1021/ja101673v