methyl 5-acetamido-4,7,8,9-tetra-O-acetyl-5-deoxy-3-S-phenyl-3-thio-D-erythro-β-L-gluco-2-nonulopyranosonate

Base Information

Chemical Name:methyl 5-acetamido-4,7,8,9-tetra-O-acetyl-5-deoxy-3-S-phenyl-3-thio-D-erythro-β-L-gluco-2-nonulopyranosonate
CAS No.:140484-47-5
Molecular Formula:C₂₆H₃₃NO₁₃S
Molecular Weight:599.613
Hs Code.:

Synonyms:methyl 5-acetamido-4,7,8,9-tetra-O-acetyl-5-deoxy-3-S-phenyl-3-thio-D-erythro-β-L-gluco-2-nonulopyranosonate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 5-acetamido-4,7,8,9-tetra-O-acetyl-5-deoxy-3-S-phenyl-3-thio-D-erythro-β-L-gluco-2-nonulopyranosonate

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Technology Process of methyl 5-acetamido-4,7,8,9-tetra-O-acetyl-5-deoxy-3-S-phenyl-3-thio-D-erythro-β-L-gluco-2-nonulopyranosonate

There total 1 articles about methyl 5-acetamido-4,7,8,9-tetra-O-acetyl-5-deoxy-3-S-phenyl-3-thio-D-erythro-β-L-gluco-2-nonulopyranosonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 120123-59-3
methyl 5-acetamido-4,7,8,9-tetra-O-acetyl-2-chloro-2,5-dideoxy-3-S-phenyl-3-thio-D-erythro-β-L-gluco-2-nonulopyranosonate

: 140484-47-5
methyl 5-acetamido-4,7,8,9-tetra-O-acetyl-5-deoxy-3-S-phenyl-3-thio-D-erythro-β-L-gluco-2-nonulopyranosonate

Guidance literature:: With mercury(II) cyanide; mercury dibromide; In water; 1,2-dichloro-ethane; at 70 ℃; for 4h;
DOI:10.1016/0008-6215(92)84099-E

Reference yield:

: 140484-47-5
methyl 5-acetamido-4,7,8,9-tetra-O-acetyl-5-deoxy-3-S-phenyl-3-thio-D-erythro-β-L-gluco-2-nonulopyranosonate

: 140484-48-6
methyl 5-acetamido-4,7,8,9-tetra-O-acetyl-2-bromo-2,5-dideoxy-3-S-phenyl-3-thio-D-erythro-β-L-gluco-2-nonulopyranosonate

Guidance literature:: With N,N,N,N,N,N-hexamethylphosphoric triamide; carbon tetrabromide; In tetrahydrofuran; for 10h; Ambient temperature;
DOI:10.1016/0008-6215(92)84099-E

Reference yield:

: 140484-47-5
methyl 5-acetamido-4,7,8,9-tetra-O-acetyl-5-deoxy-3-S-phenyl-3-thio-D-erythro-β-L-gluco-2-nonulopyranosonate

: 140484-46-4
methyl <2-(benzyloxy)ethyl 5-acetamido-4,7,8,9-tetra-O-acetyl-3,5-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosid>onate

Guidance literature:: Multi-step reaction with 3 steps

1: 0.66 g / CBr₄, hexamethylphosphoric triamide (HMPT) / tetrahydrofuran / 10 h / Ambient temperature

2: 52 percent / Na₂HPO₄, 4A molecular sieves, AgOSO₂CF₃ / 15 h / Ambient temperature

3: 97 percent / Ph₃SnH, azobis(isobutano)nitrile (AIBN) / toluene / 3 h / 110 °C

With N,N,N,N,N,N-hexamethylphosphoric triamide; disodium hydrogenphosphate; 2,2'-azobis(isobutyronitrile); carbon tetrabromide; 4 A molecular sieve; triphenylstannane; silver trifluoromethanesulfonate; In tetrahydrofuran; toluene;
DOI:10.1016/0008-6215(92)84099-E