[Rh(CO)Cl(SP(C₆H₅)3)2]

Base Information

Chemical Name:[Rh(CO)Cl(SP(C₆H₅)3)2]
CAS No.:74452-83-8
Molecular Formula:C₃₇H₃₀ClOP₂RhS₂
Molecular Weight:755.083
Hs Code.:

[Rh(CO)Cl(SP(C<sub>6</sub>H<sub>5</sub>)3)2]

Synonyms:[Rh(CO)Cl(SP(C₆H₅)3)2]

Suppliers and Price of [Rh(CO)Cl(SP(C₆H₅)3)2]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [Rh(CO)Cl(SP(C₆H₅)3)2]

Chemical Property:

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Technology Process of [Rh(CO)Cl(SP(C₆H₅)3)2]

There total 3 articles about [Rh(CO)Cl(SP(C₆H₅)3)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 10.0%

: 14694-95-2
Wilkinson's catalyst

: 15318-33-9,16353-77-8,13938-94-8
chlorocarbonylbis(triphenylphosphine)rhodium(I)

: 74452-83-8
[Rh(CO)Cl(SP(C₆H₅)3)2]

Guidance literature:: With carbon oxide sulfide; In methanol; dichloromethane; addn. of COS-satd. MeOH to soln. of Rh-complex in CH2Cl2, refluxing (3 h, pptn.); filtration, washing (alcohol, ether), drying (vac.); elem. anal.;
DOI:10.1016/S0020-1693(00)91983-2

Reference yield:

: 14694-95-2
Wilkinson's catalyst

: 463-58-1
carbon oxide sulfide

: 603-35-0
triphenylphosphine

: 15318-33-9,16353-77-8,13938-94-8
chlorocarbonylbis(triphenylphosphine)rhodium(I)

: 74452-83-8
[Rh(CO)Cl(SP(C₆H₅)3)2]

Guidance literature:: In methanol; dichloromethane; Irradiation (UV/VIS); addn. of methanolic soln. of COS to a soln. of Rh(I) complex and P(C6H5)3 in CH2Cl2; filling up with methanol; irradiation (at about 250nm), 30min, stirring; crystn.; react. mechanism discussed;; filtration; washing (CH3OH/ether); drying; concn. of reddish brown filtrate in a flash evaporator at 75°C, reduced pressure; cooling of deep brown soln.; filtration; washing residue with ether; dissoln. in CH2Cl2; repptn.; drying; elem. anal.;;

Reference yield:

: 14694-95-2
Wilkinson's catalyst

: 74452-83-8
[Rh(CO)Cl(SP(C₆H₅)3)2]

Guidance literature:: With carbon oxide sulfide; triphenylphosphine; In dichloromethane; concn. (water bath or room temp.);
DOI:10.1016/S0020-1693(00)91983-2