(2E,2'E)-N,N'-(2,2'-disulfanediylbis(ethane-2,1-diyl))bis(3-(3-bromo)-(4-(dimethylamino)phenyl)-2-(hydroxyimino)propanamide)

Base Information

Chemical Name:(2E,2'E)-N,N'-(2,2'-disulfanediylbis(ethane-2,1-diyl))bis(3-(3-bromo)-(4-(dimethylamino)phenyl)-2-(hydroxyimino)propanamide)
CAS No.:1268849-23-5
Molecular Formula:C₂₆H₃₄Br₂N₆O₄S₂
Molecular Weight:718.534
Hs Code.:

Synonyms:(2E,2'E)-N,N'-(2,2'-disulfanediylbis(ethane-2,1-diyl))bis(3-(3-bromo)-(4-(dimethylamino)phenyl)-2-(hydroxyimino)propanamide)

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Chemical Property of (2E,2'E)-N,N'-(2,2'-disulfanediylbis(ethane-2,1-diyl))bis(3-(3-bromo)-(4-(dimethylamino)phenyl)-2-(hydroxyimino)propanamide)

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Technology Process of (2E,2'E)-N,N'-(2,2'-disulfanediylbis(ethane-2,1-diyl))bis(3-(3-bromo)-(4-(dimethylamino)phenyl)-2-(hydroxyimino)propanamide)

There total 6 articles about (2E,2'E)-N,N'-(2,2'-disulfanediylbis(ethane-2,1-diyl))bis(3-(3-bromo)-(4-(dimethylamino)phenyl)-2-(hydroxyimino)propanamide) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 34.0%

: 51-85-4
2,2'-dithio-bis[ethylamine]

: methyl 3-(3-bromo-4-(dimethylamino)phenyl)-2-(hydroxyimino)propanoate

: 1268849-23-5
(2E,2'E)-N,N'-(2,2'-disulfanediylbis(ethane-2,1-diyl))bis(3-(3-bromo)-(4-(dimethylamino)phenyl)-2-(hydroxyimino)propanamide)

Guidance literature:: 2,2'-dithio-bis[ethylamine]; With trimethylaluminum; In hexane; dichloromethane; acetonitrile; at 20 ℃; for 1h; Inert atmosphere; Sealed tube;

methyl 3-(3-bromo-4-(dimethylamino)phenyl)-2-(hydroxyimino)propanoate; In hexane; dichloromethane; acetonitrile; Inert atmosphere; Reflux; Sealed tubeaturated gas;
DOI:10.1039/c0ob00824a

Reference yield:

: methyl 3-(4-(dimethylamino)phenyl)-2,3-dihydroxypropanoate

: 1268849-23-5
(2E,2'E)-N,N'-(2,2'-disulfanediylbis(ethane-2,1-diyl))bis(3-(3-bromo)-(4-(dimethylamino)phenyl)-2-(hydroxyimino)propanamide)

Guidance literature:: Multi-step reaction with 3 steps

1.1: N-Bromosuccinimide / N,N-dimethyl-formamide / 2 h / 20 °C / Inert atmosphere

2.1: toluene-4-sulfonic acid / benzene / 36 h / Reflux; Inert atmosphere

3.1: trimethylaluminum / hexane; dichloromethane; acetonitrile / 1 h / 20 °C / Inert atmosphere; Sealed tube

3.2: Inert atmosphere; Reflux; Sealed tubeaturated gas

With N-Bromosuccinimide; trimethylaluminum; toluene-4-sulfonic acid; In hexane; dichloromethane; N,N-dimethyl-formamide; acetonitrile; benzene;
DOI:10.1039/c0ob00824a

Reference yield:

: 586-77-6
4-bromo-N,N-dimethylaniline

: 1268849-23-5
(2E,2'E)-N,N'-(2,2'-disulfanediylbis(ethane-2,1-diyl))bis(3-(3-bromo)-(4-(dimethylamino)phenyl)-2-(hydroxyimino)propanamide)

Guidance literature:: Multi-step reaction with 5 steps

1.1: palladium diacetate; triethylamine; tris-(o-tolyl)phosphine / N,N-dimethyl-formamide / 20 - 140 °C / Inert atmosphere

2.1: osmium(VIII) oxide; water; 4-methylmorpholine N-oxide / acetonitrile; tert-butyl alcohol / 36 h / 20 °C / Inert atmosphere

3.1: N-Bromosuccinimide / N,N-dimethyl-formamide / 2 h / 20 °C / Inert atmosphere

4.1: toluene-4-sulfonic acid / benzene / 36 h / Reflux; Inert atmosphere

5.1: trimethylaluminum / hexane; dichloromethane; acetonitrile / 1 h / 20 °C / Inert atmosphere; Sealed tube

5.2: Inert atmosphere; Reflux; Sealed tubeaturated gas

With N-Bromosuccinimide; osmium(VIII) oxide; water; trimethylaluminum; palladium diacetate; toluene-4-sulfonic acid; 4-methylmorpholine N-oxide; triethylamine; tris-(o-tolyl)phosphine; In hexane; dichloromethane; N,N-dimethyl-formamide; acetonitrile; tert-butyl alcohol; benzene; 1.1: Heck reaction;
DOI:10.1039/c0ob00824a