(OC)Rh((CH₃)3C)2PCH₂CH₂CHCHCH₂CH₂P(C(CH₃)3)2⁽¹⁺⁾*B(C₆H₅)4^(1-) = ((OC)Rh((CH₃)3C)2PCH₂CH₂CHCHCH₂CH₂P(C(CH₃)3)2)B(C₆H₅)4

Base Information

• Chemical Name: (OC)Rh((CH₃)3C)2PCH₂CH₂CHCHCH₂CH₂P(C(CH₃)3)2⁽¹⁺⁾*B(C₆H₅)4^(1-) = ((OC)Rh((CH₃)3C)2PCH₂CH₂CHCHCH₂CH₂P(C(CH₃)3)2)B(C₆H₅)4
• CAS No.: 74751-93-2
• Molecular Formula: C₂₃H₄₆OP₂Rh*C₂₄H₂₀B
• Molecular Weight: 822.704
• Mol file: 74751-93-2.mol

Synonyms:(OC)Rh((CH₃)3C)2PCH₂CH₂CHCHCH₂CH₂P(C(CH₃)3)2⁽¹⁺⁾*B(C₆H₅)4^(1-) = ((OC)Rh((CH₃)3C)2PCH₂CH₂CHCHCH₂CH₂P(C(CH₃)3)2)B(C₆H₅)4

Chemical Property of (OC)Rh((CH₃)3C)2PCH₂CH₂CHCHCH₂CH₂P(C(CH₃)3)2⁽¹⁺⁾*B(C₆H₅)4^(1-) = ((OC)Rh((CH₃)3C)2PCH₂CH₂CHCHCH₂CH₂P(C(CH₃)3)2)B(C₆H₅)4

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of (OC)Rh((CH₃)3C)2PCH₂CH₂CHCHCH₂CH₂P(C(CH₃)3)2⁽¹⁺⁾*B(C₆H₅)4^(1-) = ((OC)Rh((CH₃)3C)2PCH₂CH₂CHCHCH₂CH₂P(C(CH₃)3)2)B(C₆H₅)4

There total 2 articles about (OC)Rh((CH₃)3C)2PCH₂CH₂CHCHCH₂CH₂P(C(CH₃)3)2⁽¹⁺⁾*B(C₆H₅)4^(1-) = ((OC)Rh((CH₃)3C)2PCH₂CH₂CHCHCH₂CH₂P(C(CH₃)3)2)B(C₆H₅)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

ClRh((CH3)3C)2PCH2CH2CHCHCH2CH2P(C(CH3)3)2 (60118-88-9) + sodium tetraphenyl borate (143-66-8) → (OC)Rh((CH3)3C)2PCH2CH2CHCHCH2CH2P(C(CH3)3)2(1+)*B(C6H5)4(1-) = ((OC)Rh((CH3)3C)2PCH2CH2CHCHCH2CH2P(C(CH3)3)2)B(C6H5)4 (74751-93-2)

Guidance literature:

With CO; In ethanol; CO bubbled through soln. of Rh-complex to which had been added a soln. of B(C6H5)4 (fourfold excess), 2 h; water slowly added; elem. anal.;

DOI:10.1021/ja00533a014

Reference yield:

1,6-bis(di-t-butylphosphino)hexane (72974-19-7) → (OC)Rh((CH3)3C)2PCH2CH2CHCHCH2CH2P(C(CH3)3)2(1+)*B(C6H5)4(1-) = ((OC)Rh((CH3)3C)2PCH2CH2CHCHCH2CH2P(C(CH3)3)2)B(C6H5)4 (74751-93-2)

Guidance literature:

Multi-step reaction with 2 steps

1: isopropyl alcohol

2: CO / ethanol

With CO; In ethanol; isopropyl alcohol;

DOI:10.1021/ja00533a014

upstream raw materials:

ClRh((CH₃)3C)2PCH₂CH₂CHCHCH₂CH₂P(C(CH₃)3)2

sodium tetraphenyl borate

1,6-bis(di-t-butylphosphino)hexane