(E)-2-methyl-6-(3,4-dimethoxyphenyl)-2-hexenyl 2-tetrahydropyranyl ether

Base Information

Chemical Name:(E)-2-methyl-6-(3,4-dimethoxyphenyl)-2-hexenyl 2-tetrahydropyranyl ether
CAS No.:117582-44-2
Molecular Formula:C₂₀H₃₀O₄
Molecular Weight:334.456
Hs Code.:

Synonyms:(E)-2-methyl-6-(3,4-dimethoxyphenyl)-2-hexenyl 2-tetrahydropyranyl ether

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Chemical Property of (E)-2-methyl-6-(3,4-dimethoxyphenyl)-2-hexenyl 2-tetrahydropyranyl ether

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Technology Process of (E)-2-methyl-6-(3,4-dimethoxyphenyl)-2-hexenyl 2-tetrahydropyranyl ether

There total 2 articles about (E)-2-methyl-6-(3,4-dimethoxyphenyl)-2-hexenyl 2-tetrahydropyranyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 121213-49-8
9-((CH₂)3(C₆H₄)(OMe)2)-9-borabicyclo{3.3.1}nonane

: 126847-91-4
(E)-3-bromo-2-methyl-2-propenyl 2-tetrahydropyranyl ether

: 117582-44-2
(E)-2-methyl-6-(3,4-dimethoxyphenyl)-2-hexenyl 2-tetrahydropyranyl ether

Guidance literature:: With sodium hydroxide; dihydrogen peroxide; cis-dichloro-1,1'-bis(diphenylphosphino)ferrocene palladium(II); In tetrahydrofuran; To a soln. of 9-((CH2)3(C6H3)(OMe))-9-BBN is added THPOCH2C(CH3)CHBr, THF and aq. NaOH at room Temp., mixt. refluxed overnight (14-16 h), react. mixt. diluted with hexane or benzene, residue oxidized by H2O2 at room temp.; Extracted, washed with brine, dried (MgSO4), when a product is sensitive to NaOH/H2O, the extract is subjected to column chromy., final product is identified by mass spectrometry, IR, elem. anal.;
DOI:10.1021/ja00183a048

Reference yield:

: 93-15-2
1,2-dimethoxy-4-(2-propenyl)benzene

: 126847-91-4
(E)-3-bromo-2-methyl-2-propenyl 2-tetrahydropyranyl ether

: 117582-44-2
(E)-2-methyl-6-(3,4-dimethoxyphenyl)-2-hexenyl 2-tetrahydropyranyl ether

Guidance literature:: With sodium hydroxide; 9-borabicyclo[3.3.1]nonane dimer; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; Yield given. Multistep reaction; 1.) THF, r.t., 6 h; 2.) THF, 65 deg C, 16 h;
DOI:10.1021/ja00183a048