Rh((R,R)-μ-1,3-phenylenebis[1,1'-(3,3'-di-tert-butyl-5,5',6,6'-tetramethyl)biphen-2,2'-diyl]diphosphite(-1H))(PPh3)

Base Information

Chemical Name:Rh((R,R)-μ-1,3-phenylenebis[1,1'-(3,3'-di-tert-butyl-5,5',6,6'-tetramethyl)biphen-2,2'-diyl]diphosphite(-1H))(PPh3)
CAS No.:927866-15-7
Molecular Formula:C₇₂H₈₂O₆P₃Rh
Molecular Weight:1239.27
Hs Code.:

Synonyms:Rh((R,R)-μ-1,3-phenylenebis[1,1'-(3,3'-di-tert-butyl-5,5',6,6'-tetramethyl)biphen-2,2'-diyl]diphosphite(-1H))(PPh3)

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Chemical Property of Rh((R,R)-μ-1,3-phenylenebis[1,1'-(3,3'-di-tert-butyl-5,5',6,6'-tetramethyl)biphen-2,2'-diyl]diphosphite(-1H))(PPh3)

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Technology Process of Rh((R,R)-μ-1,3-phenylenebis[1,1'-(3,3'-di-tert-butyl-5,5',6,6'-tetramethyl)biphen-2,2'-diyl]diphosphite(-1H))(PPh3)

There total 1 articles about Rh((R,R)-μ-1,3-phenylenebis[1,1'-(3,3'-di-tert-butyl-5,5',6,6'-tetramethyl)biphen-2,2'-diyl]diphosphite(-1H))(PPh3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 14694-95-2
Wilkinson's catalyst

: 1100752-22-4
(R,R)-μ-1,3-phenylenebis[1,1'-(3,3'-di-tert-butyl-5,5',6,6'-tetramethyl)biphen-2,2'-diyl]diphosphite

: 927866-15-7
Rh((R,R)-μ-1,3-phenylenebis[1,1'-(3,3'-di-tert-butyl-5,5',6,6'-tetramethyl)biphen-2,2'-diyl]diphosphite(-1H))(PPh3)

Guidance literature:: With NEt₃; In tetrahydrofuran; under N2; ligand in THF added over suspn. of Rh complex in THF; heated at 60°C for 16 h; NEt3 (excess) added; stirred at 60°C for 24 h; solvent removed under reduced pressure; purified by column chromy. (silica gel, AcOEt-hexane 1:20); elem. anal.;
DOI:10.1021/om800830w