4,4-di-η(5)-cyclopentadienyl-2-(2,4,6-tris[bis(triemthylsilyl)methyl]phenyl)-1,3,2,4-dithiaboratitanetane

Base Information

• Chemical Name: 4,4-di-η(5)-cyclopentadienyl-2-(2,4,6-tris[bis(triemthylsilyl)methyl]phenyl)-1,3,2,4-dithiaboratitanetane
• CAS No.: 170958-45-9
• Molecular Formula: C₃₇H₆₉BS₂Si₆Ti
• Molecular Weight: 805.291
• Mol file: 170958-45-9.mol

Synonyms:4,4-di-η(5)-cyclopentadienyl-2-(2,4,6-tris[bis(triemthylsilyl)methyl]phenyl)-1,3,2,4-dithiaboratitanetane

Chemical Property of 4,4-di-η(5)-cyclopentadienyl-2-(2,4,6-tris[bis(triemthylsilyl)methyl]phenyl)-1,3,2,4-dithiaboratitanetane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4,4-di-η(5)-cyclopentadienyl-2-(2,4,6-tris[bis(triemthylsilyl)methyl]phenyl)-1,3,2,4-dithiaboratitanetane

There total 2 articles about 4,4-di-η(5)-cyclopentadienyl-2-(2,4,6-tris[bis(triemthylsilyl)methyl]phenyl)-1,3,2,4-dithiaboratitanetane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

bis(cyclopentadienyl)titanium dichloride (1271-19-8) + (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)dimercaptoborane (170958-44-8) → 4,4-di-η(5)-cyclopentadienyl-2-(2,4,6-tris[bis(triemthylsilyl)methyl]phenyl)-1,3,2,4-dithiaboratitanetane (170958-45-9)

Guidance literature:

With n-BuLi; In tetrahydrofuran; hexane; Ar-atmosphere; stirring (-78°C, 2 h), Cp2TiCl2 addn.; evapn. (room temp.), chromy. (SiO2, hexane); elem. anal.;

DOI:10.1021/om970328+

Reference yield:

dibromobis(cyclopentadienyl)titanium(IV) + (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)dimercaptoborane (170958-44-8) → 4,4-di-η(5)-cyclopentadienyl-2-(2,4,6-tris[bis(triemthylsilyl)methyl]phenyl)-1,3,2,4-dithiaboratitanetane (170958-45-9)

Guidance literature:

With n-butyllithium;

DOI:10.1080/10426509708545677

upstream raw materials:

(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)dimercaptoborane

bis(cyclopentadienyl)titanium dichloride