OsHCl(phosphorus trichloride)(CO)(triphenylphosphine)2

Base Information

• Chemical Name: OsHCl(phosphorus trichloride)(CO)(triphenylphosphine)2
• CAS No.: 133377-32-9
• Molecular Formula: C₃₇H₃₁Cl₄OOsP₃
• Molecular Weight: 916.586
• Mol file: 133377-32-9.mol

Synonyms:OsHCl(phosphorus trichloride)(CO)(triphenylphosphine)2

Chemical Property of OsHCl(phosphorus trichloride)(CO)(triphenylphosphine)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of OsHCl(phosphorus trichloride)(CO)(triphenylphosphine)2

There total 1 articles about OsHCl(phosphorus trichloride)(CO)(triphenylphosphine)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hydridocarbonylchlorotris(triphenylphosphine)osmium(II) (16971-31-6,36007-23-5) → OsHCl(phosphorus trichloride)(CO)(triphenylphosphine)2 (133377-32-9)

Guidance literature:

With PCl₃; In benzene; suspn. of Os-compd. in C6H6, addn. of excess PCl3, heating at reflux for 2 h, 10 min react. (clear soln.), cooling; evapn. (vac.), recrystn. from CH2Cl2/ethanol; elem. anal.;

DOI:10.1016/0022-328X(91)86251-K

Reference yield: 96.0%

OsHCl(phosphorus trichloride)(CO)(triphenylphosphine)2 (133377-32-9) → OsCl2(phosphorus trichloride)(CO)(triphenylphosphine)2 (133317-55-2,133442-78-1)

Guidance literature:

With Cl₂; In tetrachloromethane; dichloromethane; byproducts: HCl; treatment of Os-complex in CH2Cl2 with a soln. of Cl2 in CCl4, 12 h react.; mixture of cis/trans isomers (Cl ligands); evapn. (vac.), recrystn. from CH2Cl2/C2H5OH; elem. anal.;

DOI:10.1016/0022-328X(91)86251-K

Reference yield: 60.0%

OsHCl(phosphorus trichloride)(CO)(triphenylphosphine)2 (133377-32-9) → OsH2(PH3)(CO)(PPh3)2 (112490-02-5,116947-28-5)

Guidance literature:

With LiB(C₂H₅)3H; In not given; react. of Os-compd. with LiBEt3H;

DOI:10.1016/0022-328X(91)86251-K

upstream raw materials:

hydridocarbonylchlorotris(triphenylphosphine)osmium(II)

Downstream raw materials:

OsH₂(PH₃)(CO)(PPh₃)2

OsCl₂(phosphorus trichloride)(CO)(triphenylphosphine)2