Technology Process of 1-methyl(diphenyl)silyl-2,3,5-triphenylbenzene
There total 6 articles about 1-methyl(diphenyl)silyl-2,3,5-triphenylbenzene which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
tetrakis(triphenylphosphine) palladium(0); tetrabutyl ammonium fluoride; silver(l) oxide;
In
tetrahydrofuran;
at 65 ℃;
for 16h;
Inert atmosphere;
DOI:10.1021/ol4010883
- Guidance literature:
-
Multi-step reaction with 4 steps
1: palladium diacetate; N-ethyl-N,N-diisopropylamine / 24 h / 30 °C
2: lithium aluminium tetrahydride / 1,4-dioxane / 18 h / 80 °C / Inert atmosphere
3: palladium 10% on activated carbon / water; pentane / 6 h / 20 °C / Inert atmosphere
4: tetrakis(triphenylphosphine) palladium(0); tetrabutyl ammonium fluoride; silver(l) oxide / tetrahydrofuran / 16 h / 65 °C / Inert atmosphere
With
lithium aluminium tetrahydride; tetrakis(triphenylphosphine) palladium(0); palladium 10% on activated carbon; tetrabutyl ammonium fluoride; palladium diacetate; N-ethyl-N,N-diisopropylamine; silver(l) oxide;
In
tetrahydrofuran; 1,4-dioxane; water; pentane;
4: |Hiyama Coupling;
DOI:10.1021/ol4010883
- Guidance literature:
-
Multi-step reaction with 3 steps
1: lithium aluminium tetrahydride / 1,4-dioxane / 18 h / 80 °C / Inert atmosphere
2: palladium 10% on activated carbon / water; pentane / 6 h / 20 °C / Inert atmosphere
3: tetrakis(triphenylphosphine) palladium(0); tetrabutyl ammonium fluoride; silver(l) oxide / tetrahydrofuran / 16 h / 65 °C / Inert atmosphere
With
lithium aluminium tetrahydride; tetrakis(triphenylphosphine) palladium(0); palladium 10% on activated carbon; tetrabutyl ammonium fluoride; silver(l) oxide;
In
tetrahydrofuran; 1,4-dioxane; water; pentane;
3: |Hiyama Coupling;
DOI:10.1021/ol4010883
