(R)-1-methylheptyl 4'-[4-(hex-5-enyloxy)benzoyloxy]biphenyl-4-carboxylate

Base Information

Chemical Name:(R)-1-methylheptyl 4'-[4-(hex-5-enyloxy)benzoyloxy]biphenyl-4-carboxylate
CAS No.:240133-73-7
Molecular Formula:C₃₄H₄₀O₅
Molecular Weight:528.689
Hs Code.:

Synonyms:(R)-1-methylheptyl 4'-[4-(hex-5-enyloxy)benzoyloxy]biphenyl-4-carboxylate

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Chemical Property of (R)-1-methylheptyl 4'-[4-(hex-5-enyloxy)benzoyloxy]biphenyl-4-carboxylate

Chemical Property:

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Technology Process of (R)-1-methylheptyl 4'-[4-(hex-5-enyloxy)benzoyloxy]biphenyl-4-carboxylate

There total 4 articles about (R)-1-methylheptyl 4'-[4-(hex-5-enyloxy)benzoyloxy]biphenyl-4-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 115595-28-3
4-(hex-5-en-1-yloxy)benzoic acid

: 121687-76-1
4'-hydroxy-biphenyl-4-carboxylic acid (R)-1-methyl-heptyl ester

: 240133-73-7
(R)-1-methylheptyl 4'-[4-(hex-5-enyloxy)benzoyloxy]biphenyl-4-carboxylate

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃; for 24h;
DOI:10.1039/a809842e

Reference yield:

: 821-41-0
5-Hexen-1-ol

: 240133-73-7
(R)-1-methylheptyl 4'-[4-(hex-5-enyloxy)benzoyloxy]biphenyl-4-carboxylate

Guidance literature:: Multi-step reaction with 4 steps

1.1: 88 percent / KI; pyridine / 4 h / 0 °C

2.1: NaH / dimethylformamide / 1 h / 5 °C

2.2: 69 percent / dimethylformamide / 20 h / 80 °C

3.1: 82 percent / 5 percent aq. KOH / ethanol / 4 h / Heating

4.1: 56 percent / DCC; DMAP / CH₂Cl₂ / 24 h / 20 °C

With pyridine; dmap; potassium hydroxide; sodium hydride; dicyclohexyl-carbodiimide; potassium iodide; In ethanol; dichloromethane; N,N-dimethyl-formamide; 1.1: Tosylation / 2.1: deprotonation / 2.2: Alkylation / 3.1: Hydrolysis / 4.1: Esterification;
DOI:10.1039/a809842e

Reference yield:

: 18922-06-0
hex-5-enyl 4-methylbenzenesulfonate

: 240133-73-7
(R)-1-methylheptyl 4'-[4-(hex-5-enyloxy)benzoyloxy]biphenyl-4-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1.1: NaH / dimethylformamide / 1 h / 5 °C

1.2: 69 percent / dimethylformamide / 20 h / 80 °C

2.1: 82 percent / 5 percent aq. KOH / ethanol / 4 h / Heating

3.1: 56 percent / DCC; DMAP / CH₂Cl₂ / 24 h / 20 °C

With dmap; potassium hydroxide; sodium hydride; dicyclohexyl-carbodiimide; In ethanol; dichloromethane; N,N-dimethyl-formamide; 1.1: deprotonation / 1.2: Alkylation / 2.1: Hydrolysis / 3.1: Esterification;
DOI:10.1039/a809842e