1,1'-bis(N,N-dimethylamino)titanocene dichloride

Base Information

• Chemical Name: 1,1'-bis(N,N-dimethylamino)titanocene dichloride
• CAS No.: 95144-45-9
• Molecular Formula: C₁₄H₂₀Cl₂N₂Ti
• Molecular Weight: 335.112
• Mol file: 95144-45-9.mol

Synonyms:1,1'-bis(N,N-dimethylamino)titanocene dichloride

Chemical Property of 1,1'-bis(N,N-dimethylamino)titanocene dichloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,1'-bis(N,N-dimethylamino)titanocene dichloride

There total 1 articles about 1,1'-bis(N,N-dimethylamino)titanocene dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 14.0%

cyclopentadienyl titanium(IV) trichloride (1270-98-0) + N,N-dimethylamino-cyclopentadienyllithium (75812-66-7) → bis(cyclopentadienyl)titanium dichloride (1271-19-8) + 1,1'-bis(N,N-dimethylamino)titanocene dichloride (95144-45-9)

Guidance literature:

In tetrahydrofuran; under N2; to soln. of LiC5H4NMe2 in THF added at -30 °C soln. ofCpTiCl3 in THF, kept for 12 h at room temp.; evapd., extd. (CHCl3), evapd., pptd. (C5H4NMe2)2TiCl2 by addn. of pentane, recrystd. (CHCl3); CHCl3 soln. contained Cp2TiCl2;

DOI:10.1016/0022-328X(84)80686-5

upstream raw materials:

cyclopentadienyl titanium(IV) trichloride

N,N-dimethylamino-cyclopentadienyllithium