[5,10,15,20-tetrakis(trifluoromethyl)-2-(phenylethynyl)porphinato]zinc(II)

Base Information

Chemical Name:[5,10,15,20-tetrakis(trifluoromethyl)-2-(phenylethynyl)porphinato]zinc(II)
CAS No.:424788-36-3
Molecular Formula:C₃₂H₁₂F₁₂N₄Zn
Molecular Weight:745.845
Hs Code.:

Synonyms:[5,10,15,20-tetrakis(trifluoromethyl)-2-(phenylethynyl)porphinato]zinc(II)

Suppliers and Price of [5,10,15,20-tetrakis(trifluoromethyl)-2-(phenylethynyl)porphinato]zinc(II)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemicals and raw materials
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Total 2 raw suppliers

Chemical Property of [5,10,15,20-tetrakis(trifluoromethyl)-2-(phenylethynyl)porphinato]zinc(II)

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of [5,10,15,20-tetrakis(trifluoromethyl)-2-(phenylethynyl)porphinato]zinc(II)

There total 2 articles about [5,10,15,20-tetrakis(trifluoromethyl)-2-(phenylethynyl)porphinato]zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 310408-38-9
[2-bromo-5,10,15,20-tetrakis(trifluoromethyl)porphyrinato]zinc(II)

: 536-74-3
phenylacetylene

: 424788-36-3
[5,10,15,20-tetrakis(trifluoromethyl)-2-(phenylethynyl)porphinato]zinc(II)

Guidance literature:: With As(C₆H₅)3; (C₂H₅)3N; Pd₂(C₆H₅CHCHCOCHCHC₆H₅)3; In tetrahydrofuran; triethylamine; under N2; Zn complex, ethynylbenzene, Pd2(dba)3 and As(C6H5)3 were dissolved in THF/triethylamine (5/1), mixt. was stirred for 20 h at 40°C; solvent was evapd., residue was chromd. (silica gel, hexanes/toluene (1/1));
DOI:10.1021/ja012489h

Reference yield:

: 151811-01-7
[5,10,15,20-tetrakis(trifluoromethyl)porphinato]zinc(II)

: 424788-36-3
[5,10,15,20-tetrakis(trifluoromethyl)-2-(phenylethynyl)porphinato]zinc(II)

Guidance literature:: Multi-step reaction with 2 steps

1: methanol

2: As(C₆H₅)3; (C₂H₅)3N; Pd₂(C₆H₅CHCHCOCHCHC₆H₅)3 / tetrahydrofuran; triethylamine

With As(C₆H₅)3; (C₂H₅)3N; Pd₂(C₆H₅CHCHCOCHCHC₆H₅)3; In tetrahydrofuran; methanol; triethylamine;
DOI:10.1021/ja012489h

Reference yield: 89.0%

: 2396-63-6
hepta-1,6-diyne

: 424788-36-3
[5,10,15,20-tetrakis(trifluoromethyl)-2-(phenylethynyl)porphinato]zinc(II)

: 424788-28-3
5-phenyl-6-([2'-5',10',15',20'-tetrakis(trifluoromethyl)porphinato]zinc(II))indane

Guidance literature:: With Co₂(CO)8; In 1,4-dioxane; toluene; under N2; Zn complex and Co2(CO)8 were dissolved in toluene/dioxane (4/1) and heated to 100°C, a soln. of 1,6-heptadiyne in toluene was added dropwise (90 min); soln. was evapd. to dryness, residue was chromd. (silica gel, hexanes/toluene (1/1));
DOI:10.1021/ja012489h