trans-2-(4-[1-(R)-(tert-butyldimethylsilyloxy)hexyl]phenyl)-5-oxo-cyclopentaneheptanoic acid methyl ester

Base Information

Chemical Name:trans-2-(4-[1-(R)-(tert-butyldimethylsilyloxy)hexyl]phenyl)-5-oxo-cyclopentaneheptanoic acid methyl ester
CAS No.:856865-45-7
Molecular Formula:C₃₁H₅₂O₄Si
Molecular Weight:516.837
Hs Code.:

Synonyms:trans-2-(4-[1-(R)-(tert-butyldimethylsilyloxy)hexyl]phenyl)-5-oxo-cyclopentaneheptanoic acid methyl ester

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Chemical Property of trans-2-(4-[1-(R)-(tert-butyldimethylsilyloxy)hexyl]phenyl)-5-oxo-cyclopentaneheptanoic acid methyl ester

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Technology Process of trans-2-(4-[1-(R)-(tert-butyldimethylsilyloxy)hexyl]phenyl)-5-oxo-cyclopentaneheptanoic acid methyl ester

There total 2 articles about trans-2-(4-[1-(R)-(tert-butyldimethylsilyloxy)hexyl]phenyl)-5-oxo-cyclopentaneheptanoic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 34546-57-1
2-(6-methoxycarbonylhexyl)cyclopent-2-en-1-one

: 856865-45-7
cis-2-(4-[1-(R)-(tert-butyldimethylsilyloxy)hexyl]phenyl)-5-oxo-cyclopentaneheptanoic acid methyl ester

: 856865-45-7
trans-2-(4-[1-(R)-(tert-butyldimethylsilyloxy)hexyl]phenyl)-5-oxo-cyclopentaneheptanoic acid methyl ester

Guidance literature:: (R)-1-(4-bromophenyl)-1-(tert-butyldimethylsilyloxy)hexane; With tert.-butyl lithium; In diethyl ether; hexane; at -78 - -60 ℃; for 3h;

With 1-pentynyl copper; Hexamethylphosphorous triamide; In diethyl ether; hexane; at -78 ℃; for 1h;

2-(6-methoxycarbonylhexyl)cyclopent-2-en-1-one; In diethyl ether; hexane; at -78 - -10 ℃; for 1.25h; Product distribution / selectivity;

Reference yield:

: 34546-57-1
2-(6-methoxycarbonylhexyl)cyclopent-2-en-1-one

: 856865-45-7
cis-2-(4-[1-(R)-(tert-butyldimethylsilyloxy)hexyl]phenyl)-5-oxo-cyclopentaneheptanoic acid methyl ester

: 856865-45-7
trans-2-(4-[1-(R)-(tert-butyldimethylsilyloxy)hexyl]phenyl)-5-oxo-cyclopentaneheptanoic acid methyl ester

Guidance literature:: (R)-1-(4-bromophenyl)-1-(tert-butyldimethylsilyloxy)hexane; With tert.-butyl lithium; In diethyl ether; hexane; at -78 - -60 ℃; for 3h;

With 1-pentynyl copper; Hexamethylphosphorous triamide; In diethyl ether; hexane; at -78 ℃; for 1h;

2-(6-methoxycarbonylhexyl)cyclopent-2-en-1-one; In diethyl ether; hexane; at -78 - -10 ℃; for 1.25h; Product distribution / selectivity;