Technology Process of methyl 1-O-(5-ethoxycarbonyl-2-benzyloxyphenyl)-2,3,4-tri-O-acetyl-β-D-glucopyranosiduronate
There total 5 articles about methyl 1-O-(5-ethoxycarbonyl-2-benzyloxyphenyl)-2,3,4-tri-O-acetyl-β-D-glucopyranosiduronate which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
boron trifluoride diethyl etherate;
In
dichloromethane;
at -20 - 15 ℃;
for 4h;
Inert atmosphere;
Molecular sieve;
DOI:10.1016/j.tet.2012.03.100
- Guidance literature:
-
Multi-step reaction with 3 steps
1: potassium carbonate; potassium iodide / acetone / 24 h / Inert atmosphere; Reflux
2: water; sodium carbonate / tetrahydrofuran; methanol / 20 °C / Inert atmosphere
3: boron trifluoride diethyl etherate / dichloromethane / 4 h / -20 - 15 °C / Inert atmosphere; Molecular sieve
With
boron trifluoride diethyl etherate; water; sodium carbonate; potassium carbonate; potassium iodide;
In
tetrahydrofuran; methanol; dichloromethane; acetone;
1: Williamson synthesis;
DOI:10.1016/j.tet.2012.03.100
- Guidance literature:
-
Multi-step reaction with 3 steps
1: potassium carbonate; potassium iodide / acetone / 24 h / Inert atmosphere; Reflux
2: water; sodium carbonate / tetrahydrofuran; methanol / 20 °C / Inert atmosphere
3: boron trifluoride diethyl etherate / dichloromethane / 4 h / -20 - 15 °C / Inert atmosphere; Molecular sieve
With
boron trifluoride diethyl etherate; water; sodium carbonate; potassium carbonate; potassium iodide;
In
tetrahydrofuran; methanol; dichloromethane; acetone;
1: Williamson synthesis;
DOI:10.1016/j.tet.2012.03.100
