carbonyl(chloro)bis(di-t-butylmethylphosphane)(E-2-phenylvinyl)osmium(II)

Base Information

Chemical Name:carbonyl(chloro)bis(di-t-butylmethylphosphane)(E-2-phenylvinyl)osmium(II)
CAS No.:122115-88-2
Molecular Formula:C₂₇H₄₉ClOOsP₂
Molecular Weight:677.286
Hs Code.:

Synonyms:carbonyl(chloro)bis(di-t-butylmethylphosphane)(E-2-phenylvinyl)osmium(II)

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Chemical Property of carbonyl(chloro)bis(di-t-butylmethylphosphane)(E-2-phenylvinyl)osmium(II)

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Technology Process of carbonyl(chloro)bis(di-t-butylmethylphosphane)(E-2-phenylvinyl)osmium(II)

There total 2 articles about carbonyl(chloro)bis(di-t-butylmethylphosphane)(E-2-phenylvinyl)osmium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 104911-48-0
{hydrido(chloro)(carbonyl)bis(P(Me-t-Bu₂))}osmium(II)

: 536-74-3
phenylacetylene

: 122115-88-2
carbonyl(chloro)bis(di-t-butylmethylphosphane)(E-2-phenylvinyl)osmium(II)

Guidance literature:: In hexane; inert atmosphere; stirring for 30 min at room temp.; pptn.;; ppt. filtered off; washed with hexane; dried in vacuo; elem. anal.;;
DOI:10.1021/ja00201a024

Reference yield: 83.0%

: 124401-95-2
(acetonoxime)carbonyl(chloro)bis(di-tert-butylmethylphosphane)-hydridoosmium(II)

: 536-74-3
phenylacetylene

: 122115-88-2
carbonyl(chloro)bis(di-tert-butylmethylphosphane){(E)-2-phenylvinyl}osmium(II)

Guidance literature:: In benzene; a soln. of OsHCl(CO)(PMe(tBu)2)2 treated with PhCCH, stirred for 30 min at room temp.; evapd. in vac., mixed with hexane, violet ppt. spect. detd.;

Reference yield: 72.0%

: 122115-88-2
carbonyl(chloro)bis(di-t-butylmethylphosphane)(E-2-phenylvinyl)osmium(II)

: 122116-90-9
dicarbonyl(chloro)bis(di-t-butylmethylphosphane)(E-2-phenylvinyl)osmium(II)

Guidance literature:: With CO; In benzene; (N2); into soln. of Os complex was led CO for 2 min and stirred for 10 min at room temp.; filtered soln. was concd. in vac. and treated with MeOH, formed pptn. was filtered off, washed with MeOH and dried in vac.; elem. anal.;