(+/-)-6-(4'-methoxyphenylmethoxy)-4-(t-butyldimethylsilyloxy)-1,2-hexadiene

Base Information

Chemical Name:(+/-)-6-(4'-methoxyphenylmethoxy)-4-(t-butyldimethylsilyloxy)-1,2-hexadiene
CAS No.:154366-14-0
Molecular Formula:C₂₀H₃₂O₃Si
Molecular Weight:348.558
Hs Code.:

Synonyms:(+/-)-6-(4'-methoxyphenylmethoxy)-4-(t-butyldimethylsilyloxy)-1,2-hexadiene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (+/-)-6-(4'-methoxyphenylmethoxy)-4-(t-butyldimethylsilyloxy)-1,2-hexadiene

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Technology Process of (+/-)-6-(4'-methoxyphenylmethoxy)-4-(t-butyldimethylsilyloxy)-1,2-hexadiene

There total 6 articles about (+/-)-6-(4'-methoxyphenylmethoxy)-4-(t-butyldimethylsilyloxy)-1,2-hexadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 69739-34-0
t-butyldimethylsiyl triflate

: 154366-13-9
(+/-)-6-(4'-methoxyphenylmethoxy)-1,2-hexadien-4-ol

: 154366-14-0
(+/-)-6-(4'-methoxyphenylmethoxy)-4-(t-butyldimethylsilyloxy)-1,2-hexadiene

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; for 4h; Ambient temperature;
DOI:10.1016/0040-4020(93)80015-L

Reference yield:

: 128461-65-4
3-(p-methoxybenzyloxy)propanal

: 154366-14-0
(+/-)-6-(4'-methoxyphenylmethoxy)-4-(t-butyldimethylsilyloxy)-1,2-hexadiene

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) n-BuLi / 1.) hexane/THF, -78 deg C, 30 min, 2.) r.t., 1 h

2: 44 percent / lithium aluminum hydride / diethyl ether / 1 h / Ambient temperature

3: 99 percent / 2,6-lutidine / CH₂Cl₂ / 4 h / Ambient temperature

With 2,6-dimethylpyridine; lithium aluminium tetrahydride; n-butyllithium; In diethyl ether; dichloromethane;
DOI:10.1016/0040-4020(93)80015-L

Reference yield:

: 89238-99-3
O-(4-methoxybenzyl)-trichloroacetimidate

: 154366-14-0
(+/-)-6-(4'-methoxyphenylmethoxy)-4-(t-butyldimethylsilyloxy)-1,2-hexadiene

Guidance literature:: Multi-step reaction with 5 steps

1: pyridinium p-toluenesulfonate / Ambient temperature

2: 92 percent / pyridinium chlorochromate, magnesium sulfate / CH₂Cl₂ / 5 h / Ambient temperature

3: 1.) n-BuLi / 1.) hexane/THF, -78 deg C, 30 min, 2.) r.t., 1 h

4: 44 percent / lithium aluminum hydride / diethyl ether / 1 h / Ambient temperature

5: 99 percent / 2,6-lutidine / CH₂Cl₂ / 4 h / Ambient temperature

With 2,6-dimethylpyridine; lithium aluminium tetrahydride; n-butyllithium; pyridinium p-toluenesulfonate; magnesium sulfate; pyridinium chlorochromate; In diethyl ether; dichloromethane;
DOI:10.1016/0040-4020(93)80015-L