(R)-[η5-(1-diphenylphosphino-2-tert-butylsulfenyl)cyclopentadienyl](η4-tetraphenylcyclobutadiene)cobalt

Base Information

Chemical Name:(R)-[η5-(1-diphenylphosphino-2-tert-butylsulfenyl)cyclopentadienyl](η4-tetraphenylcyclobutadiene)cobalt
CAS No.:756524-49-9
Molecular Formula:C₄₉H₄₂CoPS
Molecular Weight:752.905
Hs Code.:

Synonyms:(R)-[η5-(1-diphenylphosphino-2-tert-butylsulfenyl)cyclopentadienyl](η4-tetraphenylcyclobutadiene)cobalt

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Chemical Property of (R)-[η5-(1-diphenylphosphino-2-tert-butylsulfenyl)cyclopentadienyl](η4-tetraphenylcyclobutadiene)cobalt

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Technology Process of (R)-[η5-(1-diphenylphosphino-2-tert-butylsulfenyl)cyclopentadienyl](η4-tetraphenylcyclobutadiene)cobalt

There total 1 articles about (R)-[η5-(1-diphenylphosphino-2-tert-butylsulfenyl)cyclopentadienyl](η4-tetraphenylcyclobutadiene)cobalt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 756524-48-8
(R(S),R(P))-[η5-(1-diphenylphosphino-2-tert-butylsulfoxide)cyclopentadienyl](η4-tetraphenylcyclobutadiene)cobalt

: 756524-49-9
(R)-[η5-(1-diphenylphosphino-2-tert-butylsulfenyl)cyclopentadienyl](η4-tetraphenylcyclobutadiene)cobalt

Guidance literature:: In toluene; treatment with HSiCl3-Et3N in refluxing toluene (ee=99.5%); HPLC;
DOI:10.1039/b405342g

Reference yield: 82.0%

: 21264-30-2,90243-59-7,14592-56-4
dichloro bis(acetonitrile) palladium(II)

: 756524-49-9
(R)-[η5-(1-diphenylphosphino-2-tert-butylsulfenyl)cyclopentadienyl](η4-tetraphenylcyclobutadiene)cobalt

: 756524-52-4
(R)-[η5-(1-diphenylphosphino-2-tert-butylsulfenyl)cyclopentadienyl](η4-tetraphenylcyclobutadiene)cobalt-PdCl2

Guidance literature:: In dichloromethane; complex (R)-(η5-(diphenylphosphino-2-tert-butylsulfenyl)cyclopentadienyl)(η4-tetraphenylcyclobutadiene) cobalt reacted with Pd(CH3CN)2Cl2 in CH2Cl2 at room temp.; XRD;
DOI:10.1039/b405342g

Reference yield:

: 26042-64-8
silver hexafluoroantimonate

: [(trans-1,3-diphenylpropenyl)palladium dichloride]2

: 756524-49-9
(R)-[η5-(1-diphenylphosphino-2-tert-butylsulfenyl)cyclopentadienyl](η4-tetraphenylcyclobutadiene)cobalt

: 756524-51-3
[η5-(1-diphenylphosphino-2-tert-butylsulfenyl)cyclopentadienyl](η4-tetraphenylcyclobutadiene)cobalt-(trans-1,3-diphenylpropenyl)palladium(1+)*SbF6(1-)

Guidance literature:: In not given; treatment of (R)-(η5-(1-diphenylphosphino-2-t-Busulfenyl)cyclopentadienyl)(η4-tetraphenylcyclobutadiene) cobalt with (trans-1,3-diphenylpropenyl palladium dichloride dimer in presence AgSbF6; NMR and XRD;
DOI:10.1039/b405342g