methyl 4-[2-(acetoxyimino)-2-[5-(cyclopentyloxycarbonyl)amino-2-(methylamino)phenyl]ethyl]-3-methoxybenzoate

Base Information

Chemical Name:methyl 4-[2-(acetoxyimino)-2-[5-(cyclopentyloxycarbonyl)amino-2-(methylamino)phenyl]ethyl]-3-methoxybenzoate
CAS No.:107786-91-4
Molecular Formula:C₂₆H₃₁N₃O₇
Molecular Weight:497.548
Hs Code.:

Synonyms:methyl 4-[2-(acetoxyimino)-2-[5-(cyclopentyloxycarbonyl)amino-2-(methylamino)phenyl]ethyl]-3-methoxybenzoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 4-[2-(acetoxyimino)-2-[5-(cyclopentyloxycarbonyl)amino-2-(methylamino)phenyl]ethyl]-3-methoxybenzoate

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Technology Process of methyl 4-[2-(acetoxyimino)-2-[5-(cyclopentyloxycarbonyl)amino-2-(methylamino)phenyl]ethyl]-3-methoxybenzoate

There total 9 articles about methyl 4-[2-(acetoxyimino)-2-[5-(cyclopentyloxycarbonyl)amino-2-(methylamino)phenyl]ethyl]-3-methoxybenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 107786-93-6
methyl 4-<2-<5-<<(cyclopentyloxy)carbonyl>amino>-2-(methylamino)phenyl>-2-(hydroxyimino)ethyl>-3-methoxybenzoate

: 108-24-7
acetic anhydride

: 107786-91-4
methyl 4-[2-(acetoxyimino)-2-[5-(cyclopentyloxycarbonyl)amino-2-(methylamino)phenyl]ethyl]-3-methoxybenzoate

Guidance literature:: With dmap; In dichloromethane; for 18h;
DOI:10.1021/jm00168a037

Reference yield:

: 107786-93-6
methyl 4-<2-<5-<<(cyclopentyloxy)carbonyl>amino>-2-(methylamino)phenyl>-2-(hydroxyimino)ethyl>-3-methoxybenzoate

: 107786-91-4
methyl 4-[2-(acetoxyimino)-2-[5-(cyclopentyloxycarbonyl)amino-2-(methylamino)phenyl]ethyl]-3-methoxybenzoate

Guidance literature:: With acetic anhydride; In dmap; dichloromethane; ethyl acetate;

Reference yield:

: 70264-94-7
methyl 4-(bromomethyl)-3-methoxybenzoate

: 107786-91-4
methyl 4-[2-(acetoxyimino)-2-[5-(cyclopentyloxycarbonyl)amino-2-(methylamino)phenyl]ethyl]-3-methoxybenzoate

Guidance literature:: Multi-step reaction with 7 steps

1: 45 percent / silver(I) oxide / dioxane / 20 h / 60 °C

2: 1.) NaH / 1.) THF, 10 min, 2.) 30 min

3: 98 percent / H₂ / 10percent Pd/C / tetrahydrofuran / 2 h / 2587.7 Torr

4: 74 percent / N-methylmorpholine / CH₂Cl₂ / 2 h

5: 98 percent / Rose Bengal, O₂ / methanol / 1.5 h / Irradiation

6: 59 percent / NH₂OH*HCl, pyridine / 18 h / Heating

7: 96 percent / 4-(dimethylamino)pyridine / CH₂Cl₂ / 18 h

With 4-methyl-morpholine; pyridine; dmap; hydroxylamine hydrochloride; hydrogen; oxygen; rose bengal; sodium hydride; silver(l) oxide; palladium on activated charcoal; In tetrahydrofuran; 1,4-dioxane; methanol; dichloromethane;
DOI:10.1021/jm00168a037