(S)-N-benzyl-1-((2S,3R)-3-((tert-butyldiphenylsilyloxy)methyl)oxiran-2-yl)pentadecan-1-amine

Base Information

Chemical Name:(S)-N-benzyl-1-((2S,3R)-3-((tert-butyldiphenylsilyloxy)methyl)oxiran-2-yl)pentadecan-1-amine
CAS No.:1254942-69-2
Molecular Formula:C₄₁H₆₁NO₂Si
Molecular Weight:628.026
Hs Code.:

Synonyms:(S)-N-benzyl-1-((2S,3R)-3-((tert-butyldiphenylsilyloxy)methyl)oxiran-2-yl)pentadecan-1-amine

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Chemical Property of (S)-N-benzyl-1-((2S,3R)-3-((tert-butyldiphenylsilyloxy)methyl)oxiran-2-yl)pentadecan-1-amine

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Technology Process of (S)-N-benzyl-1-((2S,3R)-3-((tert-butyldiphenylsilyloxy)methyl)oxiran-2-yl)pentadecan-1-amine

There total 2 articles about (S)-N-benzyl-1-((2S,3R)-3-((tert-butyldiphenylsilyloxy)methyl)oxiran-2-yl)pentadecan-1-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: Benzyl-[1-[(2S,3R)-3-(tert-butyl-diphenyl-silanyloxymethyl)-oxiranyl]-meth-(Z)-ylidene]-amine

: 110220-87-6
n-tetradecylmagnesium chloride

: 1254942-69-2
(S)-N-benzyl-1-((2S,3R)-3-((tert-butyldiphenylsilyloxy)methyl)oxiran-2-yl)pentadecan-1-amine

Guidance literature:: Benzyl-[1-[(2S,3R)-3-(tert-butyl-diphenyl-silanyloxymethyl)-oxiranyl]-meth-(Z)-ylidene]-amine; With boron trifluoride diethyl etherate; In tetrahydrofuran; at -78 - -40 ℃;

n-tetradecylmagnesium chloride; at -78 ℃; for 2h; optical yield given as %de;
DOI:10.1039/c1ob06195j

Reference yield:

: 131484-50-9
(2R,3R)-3-(((tert-butyldiphenylsilyl)oxy)methyl)oxirane-2-carbaldehyde

: 1254942-69-2
(S)-N-benzyl-1-((2S,3R)-3-((tert-butyldiphenylsilyloxy)methyl)oxiran-2-yl)pentadecan-1-amine

Guidance literature:: Multi-step reaction with 2 steps

1.1: diethyl ether / 18 h / 20 °C / Molecular sieve

2.1: boron trifluoride diethyl etherate / tetrahydrofuran / -78 - -40 °C

2.2: 2 h / -78 °C

With boron trifluoride diethyl etherate; In tetrahydrofuran; diethyl ether;
DOI:10.1039/c1ob06195j