(E)-(2-(1-((tert-butyldimethylsilyl)oxy)hexa-3,5-dien-3-yl)phenyl)(methyl)carbamic chloride

Base Information

Chemical Name:(E)-(2-(1-((tert-butyldimethylsilyl)oxy)hexa-3,5-dien-3-yl)phenyl)(methyl)carbamic chloride
CAS No.:1276611-83-6
Molecular Formula:C₂₀H₃₀ClNO₂Si
Molecular Weight:380.002
Hs Code.:

Synonyms:(E)-(2-(1-((tert-butyldimethylsilyl)oxy)hexa-3,5-dien-3-yl)phenyl)(methyl)carbamic chloride

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Chemical Property of (E)-(2-(1-((tert-butyldimethylsilyl)oxy)hexa-3,5-dien-3-yl)phenyl)(methyl)carbamic chloride

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Technology Process of (E)-(2-(1-((tert-butyldimethylsilyl)oxy)hexa-3,5-dien-3-yl)phenyl)(methyl)carbamic chloride

There total 1 articles about (E)-(2-(1-((tert-butyldimethylsilyl)oxy)hexa-3,5-dien-3-yl)phenyl)(methyl)carbamic chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 32315-10-9
bis(trichloromethyl) carbonate

: 1276612-55-5
C₁₉H₃₁NOSi

: 1276611-83-6
(E)-(2-(1-((tert-butyldimethylsilyl)oxy)hexa-3,5-dien-3-yl)phenyl)(methyl)carbamic chloride

Guidance literature:: With pyridine; In dichloromethane; at -78 ℃; for 0.5h; Inert atmosphere;
DOI:10.1021/ol2003447

Reference yield:

: 1276611-83-6
(E)-(2-(1-((tert-butyldimethylsilyl)oxy)hexa-3,5-dien-3-yl)phenyl)(methyl)carbamic chloride

: 2'-(4-bromophenyl)-1-methyl-3'-vinyl-2',3',5',6'-tetrahydrospiro[indoline-3,4'-pyran]-2-one

Guidance literature:: Multi-step reaction with 3 steps

1: bis(η3-allyl-μ-chloropalladium(II)) / 5,5-dimethyl-1,3-cyclohexadiene / 1 h / 100 °C / Inert atmosphere

2: toluene-4-sulfonic acid / water; acetonitrile / 0.5 h

3: boron trifluoride diethyl etherate / dichloromethane / 0 - 20 °C / Inert atmosphere

With bis(η3-allyl-μ-chloropalladium(II)); boron trifluoride diethyl etherate; toluene-4-sulfonic acid; In 5,5-dimethyl-1,3-cyclohexadiene; dichloromethane; water; acetonitrile; 3: Hosomi-Sakurai reaction;
DOI:10.1021/ol2003447

Reference yield:

: 1276611-83-6
(E)-(2-(1-((tert-butyldimethylsilyl)oxy)hexa-3,5-dien-3-yl)phenyl)(methyl)carbamic chloride

: 1-methyl-2'-(4-nitrophenyl)-3'-vinyl-2',3',5',6'-tetrahydrospiro[indoline-3,4'-pyran]-2-one

Guidance literature:: Multi-step reaction with 3 steps

1: bis(η3-allyl-μ-chloropalladium(II)) / 5,5-dimethyl-1,3-cyclohexadiene / 1 h / 100 °C / Inert atmosphere

2: toluene-4-sulfonic acid / water; acetonitrile / 0.5 h

3: boron trifluoride diethyl etherate / dichloromethane / 0 - 20 °C / Inert atmosphere

With bis(η3-allyl-μ-chloropalladium(II)); boron trifluoride diethyl etherate; toluene-4-sulfonic acid; In 5,5-dimethyl-1,3-cyclohexadiene; dichloromethane; water; acetonitrile; 3: Hosomi-Sakurai reaction;
DOI:10.1021/ol2003447