Technology Process of (+)-lyxo-3-(Benzoylamino)-2,3,6-trideoxyfuranohexose 5-acetate
There total 7 articles about (+)-lyxo-3-(Benzoylamino)-2,3,6-trideoxyfuranohexose 5-acetate which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
diisobutylaluminium hydride;
In
tetrahydrofuran;
at -100 ℃;
for 3h;
DOI:10.1021/jo00186a031
- Guidance literature:
-
Multi-step reaction with 7 steps
1: diethyl ether / 1.) -10 deg C, 2.) 0-5 deg C
2: 71 percent / aqueous sodium sulfite (25 percent) / diethyl ether / 0 - 5 °C / pH 7-9 (15 percent KOH), exothermic reaction
3: 1.) hydrogen chloride, 2.) sodium carbonate / 1.) room temperature, 1.5 h, 2.) Water
4: 83 percent / pyridine / Ambient temperature
5: 55 percent / trimethylamine N-oxide, osmium tetraoxide / acetone; H2O / Ambient temperature
6: 92 percent / pyridine
7: 57 percent / diisobutylaluminum hydride / tetrahydrofuran / 3 h / -100 °C
With
pyridine; hydrogenchloride; osmium(VIII) oxide; trimethylamine-N-oxide; diisobutylaluminium hydride; sodium carbonate; sodium sulfite;
In
tetrahydrofuran; diethyl ether; water; acetone;
DOI:10.1021/jo00186a031
- Guidance literature:
-
Multi-step reaction with 6 steps
1: 71 percent / aqueous sodium sulfite (25 percent) / diethyl ether / 0 - 5 °C / pH 7-9 (15 percent KOH), exothermic reaction
2: 1.) hydrogen chloride, 2.) sodium carbonate / 1.) room temperature, 1.5 h, 2.) Water
3: 83 percent / pyridine / Ambient temperature
4: 55 percent / trimethylamine N-oxide, osmium tetraoxide / acetone; H2O / Ambient temperature
5: 92 percent / pyridine
6: 57 percent / diisobutylaluminum hydride / tetrahydrofuran / 3 h / -100 °C
With
pyridine; hydrogenchloride; osmium(VIII) oxide; trimethylamine-N-oxide; diisobutylaluminium hydride; sodium carbonate; sodium sulfite;
In
tetrahydrofuran; diethyl ether; water; acetone;
DOI:10.1021/jo00186a031
