nickel(II) pyrrolo[3,4-b]5,10,15,20-tetraphenylporphyrin

Base Information

Chemical Name:nickel(II) pyrrolo[3,4-b]5,10,15,20-tetraphenylporphyrin
CAS No.:180404-43-7
Molecular Formula:C₄₆H₂₉N₅Ni
Molecular Weight:710.46
Hs Code.:

Synonyms:nickel(II) pyrrolo[3,4-b]5,10,15,20-tetraphenylporphyrin

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Chemical Property of nickel(II) pyrrolo[3,4-b]5,10,15,20-tetraphenylporphyrin

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Technology Process of nickel(II) pyrrolo[3,4-b]5,10,15,20-tetraphenylporphyrin

There total 2 articles about nickel(II) pyrrolo[3,4-b]5,10,15,20-tetraphenylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 180404-46-0
[Ni(C₄₈H₃₁N₅O₂)]

: 180404-43-7
nickel(II) pyrrolo[3,4-b]5,10,15,20-tetraphenylporphyrin

Guidance literature:: With LiCl; In dimethyl sulfoxide; demethylation with LiCl, then decarboxylation in DMSO;
DOI:10.1039/cc9960001475

Reference yield:

: 95212-88-7
nickel(II) 2-nitro-5,10,15,20-tetraphenylporphyrinate

: 180404-43-7
nickel(II) pyrrolo[3,4-b]5,10,15,20-tetraphenylporphyrin

Guidance literature:: Multi-step reaction with 2 steps

1: DBU / tetrahydrofuran; tert-butyl alcohol

2: LiCl / dimethyl sulfoxide

With DBU; LiCl; In tetrahydrofuran; dimethyl sulfoxide; tert-butyl alcohol;
DOI:10.1039/cc9960001475

Reference yield: 18.0%

: 180404-43-7
nickel(II) pyrrolo[3,4-b]5,10,15,20-tetraphenylporphyrin

: 2,5-bis[(N,N,N-trimethylammonium)methyl]-3,4-diethylpyrrole diiodide

: bis[nickel(II) 5,10,15,20-tetraphenylporphyrinato[2,3-b,l]]-7,8,17,18-tetraethylporphyrin

Guidance literature:: With potassium hexacyanoferrate(III); In tetrahydrofuran; methanol; 2,5-bis((N,N,N-trimethylammonium)methyl)-3,4-diethylpyrrole diiodide and nickel(II) pyrrolo(3,4-b)-5,10,15,20-tetraphenylporphyrin were placed in MeOH in the presence K3Fe(CN)6 and refluxed for 1 h under inert atm.; react. mixt. was diluted with CH2Cl2 and washed with H2O, 1 M HCl, and aq. NaHCO3, solvent was evapd., residue was purified by chromy. on silica with CH2Cl2/cyclohexane (2/1) as eluent, recrystn. from CH2Cl2/methanol containing 0.5 % NaOH;
DOI:10.1021/ja001316+