[(η5-trimethylsilylcyclopentadienyl)2Nb(III)(CO)(diphenylphosphanido)]

Base Information

Chemical Name:[(η5-trimethylsilylcyclopentadienyl)2Nb(III)(CO)(diphenylphosphanido)]
CAS No.:880870-87-1
Molecular Formula:C₂₉H₃₆NbOPSi₂
Molecular Weight:580.655
Hs Code.:

Synonyms:[(η5-trimethylsilylcyclopentadienyl)2Nb(III)(CO)(diphenylphosphanido)]

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Chemical Property of [(η5-trimethylsilylcyclopentadienyl)2Nb(III)(CO)(diphenylphosphanido)]

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Technology Process of [(η5-trimethylsilylcyclopentadienyl)2Nb(III)(CO)(diphenylphosphanido)]

There total 1 articles about [(η5-trimethylsilylcyclopentadienyl)2Nb(III)(CO)(diphenylphosphanido)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 290357-11-8
[Nb(η5-C5H4SiMe3)2(PHPh2)(CO)Cl]

: 880870-87-1
[(η5-trimethylsilylcyclopentadienyl)2Nb(III)(CO)(diphenylphosphanido)]

Guidance literature:: With aq. NaOH; In toluene; byproducts: NaCl, H2O; Schlenk technique; soln. of Nb complex in toluene was treated with aq. NaOH; mixt. was vigorously stirred for 4 h; filtered; evapd.; elem. anal.;
DOI:10.1021/om051013u

Reference yield: 90.0%

: 880870-87-1
[(η5-trimethylsilylcyclopentadienyl)2Nb(III)(CO)(diphenylphosphanido)]

: 4044-65-9
1 ,4-phenylenediisothiocyanate

: [(η5-C5H4SiMe3)2(CO)niobium(III)]2(μ-(κ1-S-1,4-SC(diphenylphosphanyl)N)2(C6H4))

Guidance literature:: In toluene; Nb complex treated with 0.5 equiv. of Ph(NCS)2 in dry toluene at room temp. for 15 min; filtered, washed (dry hexane) at 0°C, elem. anal.;
DOI:10.1002/ejic.200800983

Reference yield: 90.0%

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: niobium pentachloride

: 880870-87-1
[(η5-trimethylsilylcyclopentadienyl)2Nb(III)(CO)(diphenylphosphanido)]

: 1291079-00-9
[(η5-trimethylsilylcyclopentadienyl)2Nb(III)(CO)(PClPh2)][tetrachloro-oxo-tetrahydrofuran-niobate(V)]

Guidance literature:: In tetrahydrofuran; (inert atm., Schlenk technique); addn. of THF soln. of niobocene deriv. to suspn. of 1 equiv. of NbCl5 in THF at -78°C, warming to room temp., stirring for 1 h; filtration, washing with anhyd. hexane, drying in vac., elem. anal.;
DOI:10.1039/c0dt00865f