Methyl 4-O-(3,4-Di-O-acetyl-2,6-dideoxy-α-D-arabino-hexopyranosyl)-2,6-dideoxy-3-O-(p-nitrobenzoyl)-α-D-arabino-hexopyranoside

Base Information

Chemical Name:Methyl 4-O-(3,4-Di-O-acetyl-2,6-dideoxy-α-D-arabino-hexopyranosyl)-2,6-dideoxy-3-O-(p-nitrobenzoyl)-α-D-arabino-hexopyranoside
CAS No.:90762-94-0
Molecular Formula:C₂₄H₃₁NO₁₂
Molecular Weight:525.51
Hs Code.:

Synonyms:Methyl 4-O-(3,4-Di-O-acetyl-2,6-dideoxy-α-D-arabino-hexopyranosyl)-2,6-dideoxy-3-O-(p-nitrobenzoyl)-α-D-arabino-hexopyranoside

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Chemical Property of Methyl 4-O-(3,4-Di-O-acetyl-2,6-dideoxy-α-D-arabino-hexopyranosyl)-2,6-dideoxy-3-O-(p-nitrobenzoyl)-α-D-arabino-hexopyranoside

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Technology Process of Methyl 4-O-(3,4-Di-O-acetyl-2,6-dideoxy-α-D-arabino-hexopyranosyl)-2,6-dideoxy-3-O-(p-nitrobenzoyl)-α-D-arabino-hexopyranoside

There total 5 articles about Methyl 4-O-(3,4-Di-O-acetyl-2,6-dideoxy-α-D-arabino-hexopyranosyl)-2,6-dideoxy-3-O-(p-nitrobenzoyl)-α-D-arabino-hexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: 90762-91-7
Methyl 4-O-(3,4-Di-O-acteyl-2,6-dideoxy-2,6-diiodo-α-D-mannopyranosyl)-2,6-dideoxy-3-O-(p-nitrobenzoyl)-α-D-arabino-hexopyranoside

: 90762-94-0
Methyl 4-O-(3,4-Di-O-acetyl-2,6-dideoxy-α-D-arabino-hexopyranosyl)-2,6-dideoxy-3-O-(p-nitrobenzoyl)-α-D-arabino-hexopyranoside

Guidance literature:: With hydrogen; triethylamine; palladium on activated charcoal; In ethyl acetate; for 18h; Ambient temperature;
DOI:10.1021/jo00191a006

Reference yield:

: 13322-79-7
(2R,3S,4R,6S)-6-Methoxy-2-methyl-tetrahydro-pyran-3,4-diol

: 90762-94-0
Methyl 4-O-(3,4-Di-O-acetyl-2,6-dideoxy-α-D-arabino-hexopyranosyl)-2,6-dideoxy-3-O-(p-nitrobenzoyl)-α-D-arabino-hexopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 46.6 percent / pyridine / 5 °C

2: 72 percent / N-iodosuccinimide (NIS) / acetonitrile / 72 h / Ambient temperature

3: 55 percent / triethylamine, H₂ / 10percent Pd-C / ethyl acetate / 18 h / Ambient temperature

With pyridine; N-iodo-succinimide; hydrogen; triethylamine; palladium on activated charcoal; In ethyl acetate; acetonitrile;
DOI:10.1021/jo00191a006

Reference yield:

: 28413-99-2
(2S,3S,4R)-2-(iodomethyl)-3,4-dihydro-2H-pyran-3,4-diyl diacetate

: 90762-94-0
Methyl 4-O-(3,4-Di-O-acetyl-2,6-dideoxy-α-D-arabino-hexopyranosyl)-2,6-dideoxy-3-O-(p-nitrobenzoyl)-α-D-arabino-hexopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 72 percent / N-iodosuccinimide (NIS) / acetonitrile / 72 h / Ambient temperature

2: 55 percent / triethylamine, H₂ / 10percent Pd-C / ethyl acetate / 18 h / Ambient temperature

With N-iodo-succinimide; hydrogen; triethylamine; palladium on activated charcoal; In ethyl acetate; acetonitrile;
DOI:10.1021/jo00191a006