2-allylbenzenethiol

Base Information

• Chemical Name: 2-allylbenzenethiol
• CAS No.: 6165-54-4
• Molecular Formula: C₉H₁₀S
• Molecular Weight: 150.244
• Mol file: 6165-54-4.mol

Synonyms:2-allylbenzenethiol

Chemical Property of 2-allylbenzenethiol

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 2-allylbenzenethiol

There total 5 articles about 2-allylbenzenethiol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

O,S-Bis-(o-allylphenyl)-thiolcarbonat (6204-06-4) → 2-allylbenzenethiol (6165-54-4)

Guidance literature:

With ammonium hydroxide; In ethanol; at 130 - 150 ℃; for 4h;

DOI:10.1021/jo01340a016

Reference yield:

allyl phenyl thioether (5296-64-0) → 2-allylbenzenethiol (6165-54-4)

Guidance literature:

With pyridine; In various solvent(s); at 204.4 ℃; Rate constant; kinetic deuterium isotope effect; mechanism of catalysis;

DOI:10.1021/ja00397a028

Reference yield:

2-allyl-phenylamine (32704-22-6) → 2-allylbenzenethiol (6165-54-4)

Guidance literature:

Multi-step reaction with 2 steps

1.1: hydrogenchloride; sodium nitrite / water / 0.25 h / 0 °C

1.2: 20 - 45 °C

2.1: potassium hydroxide / ethanol / Reflux

With hydrogenchloride; potassium hydroxide; sodium nitrite; In ethanol; water;

DOI:10.1039/c7cc06800j

upstream raw materials:

allyl phenyl thioether

O,S-Bis-(o-allylphenyl)-thiolcarbonat

2-allyl-phenylamine

Refernces

• 1、 Yang, Zhantao,Yang, Chun-Hua,Chen, Shiqi,Chen, Xixi,Zhang, Litian,Ren, Huijun. "Catalyst free annulative thioboration of unfunctionalized olefins". . p. 12092 - 12095. Retrieved 2017/11/14.