methyl (3,4,6-tri-O-acetyl-2-trichloroacetamino-2-deoxy-β-D-glucopyranosyl)-(1->2)-(3,4-di-O-acetyl-α-L-rhamnopyranosyl)-(1->2)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl(1->3)]-4-O-benzyl-α-L-rhamnopyranoside

Base Information

Chemical Name:methyl (3,4,6-tri-O-acetyl-2-trichloroacetamino-2-deoxy-β-D-glucopyranosyl)-(1->2)-(3,4-di-O-acetyl-α-L-rhamnopyranosyl)-(1->2)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl(1->3)]-4-O-benzyl-α-L-rhamnopyranoside
CAS No.:247092-79-1
Molecular Formula:C₇₂H₈₄Cl₃NO₂₄
Molecular Weight:1453.81
Hs Code.:

methyl (3,4,6-tri-O-acetyl-2-trichloroacetamino-2-deoxy-β-D-glucopyranosyl)-(1->2)-(3,4-di-O-acetyl-α-L-rhamnopyranosyl)-(1->2)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl(1->3)]-4-O-benzyl-α-L-rhamnopyranoside

Synonyms:methyl (3,4,6-tri-O-acetyl-2-trichloroacetamino-2-deoxy-β-D-glucopyranosyl)-(1->2)-(3,4-di-O-acetyl-α-L-rhamnopyranosyl)-(1->2)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl(1->3)]-4-O-benzyl-α-L-rhamnopyranoside

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Chemical Property of methyl (3,4,6-tri-O-acetyl-2-trichloroacetamino-2-deoxy-β-D-glucopyranosyl)-(1->2)-(3,4-di-O-acetyl-α-L-rhamnopyranosyl)-(1->2)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl(1->3)]-4-O-benzyl-α-L-rhamnopyranoside

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Technology Process of methyl (3,4,6-tri-O-acetyl-2-trichloroacetamino-2-deoxy-β-D-glucopyranosyl)-(1->2)-(3,4-di-O-acetyl-α-L-rhamnopyranosyl)-(1->2)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl(1->3)]-4-O-benzyl-α-L-rhamnopyranoside

There total 12 articles about methyl (3,4,6-tri-O-acetyl-2-trichloroacetamino-2-deoxy-β-D-glucopyranosyl)-(1->2)-(3,4-di-O-acetyl-α-L-rhamnopyranosyl)-(1->2)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl(1->3)]-4-O-benzyl-α-L-rhamnopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 108-24-7
acetic anhydride

: 247092-78-0
methyl (3,4,6-tri-O-acetyl-2-trichloroacetamino-2-deoxy-β-D-glucopyranosyl)-(1->2)-α-L-rhamnopyranosyl-(1->2)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl(1->3)]-4-O-benzyl-α-L-rhamnopyranoside

: 247092-79-1
methyl (3,4,6-tri-O-acetyl-2-trichloroacetamino-2-deoxy-β-D-glucopyranosyl)-(1->2)-(3,4-di-O-acetyl-α-L-rhamnopyranosyl)-(1->2)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl(1->3)]-4-O-benzyl-α-L-rhamnopyranoside

Guidance literature:: With pyridine; for 48h;
DOI:10.1080/07328309908544033

Reference yield:

: 67773-43-7
2,3,4,6-tetra-O-benzyl-α/β-D-glucopyranosyl bromide

: 247092-79-1
methyl (3,4,6-tri-O-acetyl-2-trichloroacetamino-2-deoxy-β-D-glucopyranosyl)-(1->2)-(3,4-di-O-acetyl-α-L-rhamnopyranosyl)-(1->2)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl(1->3)]-4-O-benzyl-α-L-rhamnopyranoside

Guidance literature:: Multi-step reaction with 7 steps

1.1: dibutyltin oxide / toluene / 3 h / Heating

1.2: 36 percent / Et₃NI / CH₂Cl₂ / 96 h

2.1: 96 percent / TMSOTf / diethyl ether / 15 h / -78 - 20 °C

3.1: 98 percent / MeONa / CH₂Cl₂; methanol / 48 h / 20 °C

4.1: TMSOTf / acetonitrile / 0 - 20 °C / 89 Torr

5.1: H₂ / 1,5-COD-bis(trimethylphosphine)iridium hexafluorophosphate / tetrahydrofuran / 17 h

6.1: HgO; HgCl₂ / acetone; H₂O / 5 h / 20 °C

7.1: 98 percent / pyridine / 48 h

With pyridine; trimethylsilyl trifluoromethanesulfonate; hydrogen; sodium methylate; di(n-butyl)tin oxide; mercury dichloride; mercury(II) oxide; 1,5-COD-bis(trimethylphosphine)iridium hexafluorophosphate; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; acetone; toluene; acetonitrile; 1.1: Metallation / 1.2: Substitution / 2.1: Substitution / 3.1: Hydrolysis / 4.1: Substitution / 5.1: Isomerization / 6.1: Substitution / 7.1: Acetylation;
DOI:10.1080/07328309908544033

Reference yield:

: 25019-69-6
methyl 4-O-benzyl-α-L-rhamnopyranoside

: 247092-79-1
methyl (3,4,6-tri-O-acetyl-2-trichloroacetamino-2-deoxy-β-D-glucopyranosyl)-(1->2)-(3,4-di-O-acetyl-α-L-rhamnopyranosyl)-(1->2)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl(1->3)]-4-O-benzyl-α-L-rhamnopyranoside

Guidance literature:: Multi-step reaction with 7 steps

1.1: dibutyltin oxide / toluene / 3 h / Heating

1.2: 36 percent / Et₃NI / CH₂Cl₂ / 96 h

2.1: 96 percent / TMSOTf / diethyl ether / 15 h / -78 - 20 °C

3.1: 98 percent / MeONa / CH₂Cl₂; methanol / 48 h / 20 °C

4.1: TMSOTf / acetonitrile / 0 - 20 °C / 89 Torr

5.1: H₂ / 1,5-COD-bis(trimethylphosphine)iridium hexafluorophosphate / tetrahydrofuran / 17 h

6.1: HgO; HgCl₂ / acetone; H₂O / 5 h / 20 °C

7.1: 98 percent / pyridine / 48 h

With pyridine; trimethylsilyl trifluoromethanesulfonate; hydrogen; sodium methylate; di(n-butyl)tin oxide; mercury dichloride; mercury(II) oxide; 1,5-COD-bis(trimethylphosphine)iridium hexafluorophosphate; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; acetone; toluene; acetonitrile; 1.1: Metallation / 1.2: Substitution / 2.1: Substitution / 3.1: Hydrolysis / 4.1: Substitution / 5.1: Isomerization / 6.1: Substitution / 7.1: Acetylation;
DOI:10.1080/07328309908544033