(8R)-1-(trimethylsilyl)-8-<(4-methylphenyl)sulfonyl>amino-9-<(tert-butyldimethyl)silyl>oxonon-2-ene

Base Information

Chemical Name:(8R)-1-(trimethylsilyl)-8-<(4-methylphenyl)sulfonyl>amino-9-<(tert-butyldimethyl)silyl>oxonon-2-ene
CAS No.:226984-25-4
Molecular Formula:C₂₅H₄₇NO₃SSi₂
Molecular Weight:497.89
Hs Code.:

Synonyms:(8R)-1-(trimethylsilyl)-8-<(4-methylphenyl)sulfonyl>amino-9-<(tert-butyldimethyl)silyl>oxonon-2-ene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (8R)-1-(trimethylsilyl)-8-<(4-methylphenyl)sulfonyl>amino-9-<(tert-butyldimethyl)silyl>oxonon-2-ene

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Technology Process of (8R)-1-(trimethylsilyl)-8-<(4-methylphenyl)sulfonyl>amino-9-<(tert-butyldimethyl)silyl>oxonon-2-ene

There total 1 articles about (8R)-1-(trimethylsilyl)-8-<(4-methylphenyl)sulfonyl>amino-9-<(tert-butyldimethyl)silyl>oxonon-2-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 188816-35-5
(R)-2-(tert-butyldimethylsiloxy)methyl-1-(4-methylphenylsulfonyl)aziridine

: C₁₈H₃₈CuSi₂^(1-)*Li⁽¹⁺⁾

: 226984-25-4
(8R)-1-(trimethylsilyl)-8-<(4-methylphenyl)sulfonyl>amino-9-<(tert-butyldimethyl)silyl>oxonon-2-ene

Guidance literature:: With tributylphosphine; In diethyl ether; 1.) -78 deg C, 30 min, 2.) room temperature, 30 min;
DOI:10.1021/jo9825097

Reference yield: 91.0%

: 226984-25-4
(8R)-1-(trimethylsilyl)-8-<(4-methylphenyl)sulfonyl>amino-9-<(tert-butyldimethyl)silyl>oxonon-2-ene

: 226984-26-5
N-((Z)-(R)-1-Hydroxymethyl-8-trimethylsilanyl-oct-6-enyl)-4-methyl-benzenesulfonamide

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; for 0.5h;
DOI:10.1021/jo9825097

Reference yield:

: 226984-25-4
(8R)-1-(trimethylsilyl)-8-<(4-methylphenyl)sulfonyl>amino-9-<(tert-butyldimethyl)silyl>oxonon-2-ene

: (2R)-1-ethene-2-<(4-methylphenyl)sulfonyl>aminomethylcyclohexane

Guidance literature:: Multi-step reaction with 3 steps

1: 91 percent / n-Bu₄NF / tetrahydrofuran / 0.5 h

2: 89 percent / Ph₃P, DEAD / tetrahydrofuran / 3 h

3: 94 percent / BF₃*OEt₂ / CH₂Cl₂ / 1.) 0 deg C, 60 min, 2.) room temperature, 18 h

With boron trifluoride diethyl etherate; tetrabutyl ammonium fluoride; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo9825097