methyl 4-C-hydroxymethyl-4,5-O-isopropylidene-4'-O-tert-butyldiphenylsilyl-D-gluconate

Base Information

Chemical Name:methyl 4-C-hydroxymethyl-4,5-O-isopropylidene-4'-O-tert-butyldiphenylsilyl-D-gluconate
CAS No.:1202752-35-9
Molecular Formula:C₂₇H₃₈O₈Si
Molecular Weight:518.679
Hs Code.:

Synonyms:methyl 4-C-hydroxymethyl-4,5-O-isopropylidene-4'-O-tert-butyldiphenylsilyl-D-gluconate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 4-C-hydroxymethyl-4,5-O-isopropylidene-4'-O-tert-butyldiphenylsilyl-D-gluconate

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Technology Process of methyl 4-C-hydroxymethyl-4,5-O-isopropylidene-4'-O-tert-butyldiphenylsilyl-D-gluconate

There total 1 articles about methyl 4-C-hydroxymethyl-4,5-O-isopropylidene-4'-O-tert-butyldiphenylsilyl-D-gluconate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 1202752-24-6
(4R,5R,E)-methyl 4,5,6-trihydroxy-4-C-hydroxymethyl-4,5-O-isopropylidene-4'-O-tert-butyldiphenylsilylhex-2-enoate

: 1202752-35-9
methyl 4-C-hydroxymethyl-4,5-O-isopropylidene-4'-O-tert-butyldiphenylsilyl-D-gluconate

: 1202752-34-8
methyl 4-C-hydroxymethyl-4,5-O-isopropylidene-4'-O-tert-butyldiphenylsilyl-D-altronate

Guidance literature:: With potassium osmate(VI) dihydrate; 4-methylmorpholine N-oxide; citric acid; In water; tert-butyl alcohol; at 20 ℃; for 18h; stereospecific reaction; Inert atmosphere;
DOI:10.1016/j.tetasy.2009.08.029