propargyl 4-(2-thienyl)phenyl ether

Base Information

• Chemical Name: propargyl 4-(2-thienyl)phenyl ether
• CAS No.: 1307226-04-5
• Molecular Formula: C₁₃H₁₀OS
• Molecular Weight: 214.288
• Mol file: 1307226-04-5.mol

Synonyms:propargyl 4-(2-thienyl)phenyl ether

Chemical Property of propargyl 4-(2-thienyl)phenyl ether

Chemical Property:

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Technology Process of propargyl 4-(2-thienyl)phenyl ether

There total 1 articles about propargyl 4-(2-thienyl)phenyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

4-thiophen-2-yl-phenol (29886-65-5) + propargyl bromide (106-96-7) → propargyl 4-(2-thienyl)phenyl ether (1307226-04-5)

Guidance literature:

With potassium hydrogencarbonate; In N,N-dimethyl-formamide; at 20 ℃; for 20h;

DOI:10.1021/ic200200j

Reference yield: 60.0%

ammonium hexafluorophosphate + chloro[4'-(4-methylphenyl)-2,2':6',2''-terpyridine]platinum(II) chloride (727721-37-1) + propargyl 4-(2-thienyl)phenyl ether (1307226-04-5) → [(4'-tolyl-trpy)Pt(C.ident.C-CH2-O-C6H4-C4H3S)]PF6 (1307226-03-4)

Guidance literature:

With KOH; CuI; In methanol; water; N,N-dimethyl-formamide; (N2)' acetylene and KOH were added to methanol, stirred at room temp. for 30 min, treated with platinum complex, stirred for 48 h at room temp.,evapd. in vac.,, dissolved in DMF, aq. NH4PF6 was added, stirred for 1 h; filtered, washed with water, MeOH and Et2O, added to soln. of EtOH:MeCN (20:1), heated to reflux, filtered, elem. anal.;

DOI:10.1021/ic200200j

upstream raw materials:

4-thiophen-2-yl-phenol

propargyl bromide

Downstream raw materials:

[(4'-tolyl-trpy)Pt(C_.ident.C-CH₂-O-C₆H₄-C₄H₃S)]PF₆