5-O-<(tert-butyl)diphenylsilyl>-2-deoxy-3,4-O-isopropylidene-aldehydo-D-ribose

Base Information

Chemical Name:5-O-<(tert-butyl)diphenylsilyl>-2-deoxy-3,4-O-isopropylidene-aldehydo-D-ribose
CAS No.:135821-12-4
Molecular Formula:C₂₄H₃₂O₄Si
Molecular Weight:412.601
Hs Code.:

Synonyms:5-O-<(tert-butyl)diphenylsilyl>-2-deoxy-3,4-O-isopropylidene-aldehydo-D-ribose

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Chemical Property of 5-O-<(tert-butyl)diphenylsilyl>-2-deoxy-3,4-O-isopropylidene-aldehydo-D-ribose

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Technology Process of 5-O-<(tert-butyl)diphenylsilyl>-2-deoxy-3,4-O-isopropylidene-aldehydo-D-ribose

There total 7 articles about 5-O-<(tert-butyl)diphenylsilyl>-2-deoxy-3,4-O-isopropylidene-aldehydo-D-ribose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

: 135755-06-5
5-O-<(tert-butyl)diphenylsilyl>-2-deoxy-3,4-O-isopropylidene-D-ribose dipropyl dithioacetal

: 135821-12-4
5-O-<(tert-butyl)diphenylsilyl>-2-deoxy-3,4-O-isopropylidene-aldehydo-D-ribose

Guidance literature:: With mercury dichloride; mercury(II) oxide; In water; acetone; for 5h; Heating;
DOI:10.1002/hlca.19920750516

Reference yield:

: tert-butyl (((4R,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)methoxy)diphenylsilane

: 135821-12-4
5-O-<(tert-butyl)diphenylsilyl>-2-deoxy-3,4-O-isopropylidene-aldehydo-D-ribose

Guidance literature:: With oxygen; copper(l) chloride; palladium dichloride; In water; N,N-dimethyl-formamide; at 20 ℃; for 72h; regioselective reaction;
DOI:10.1021/acs.joc.5b00972

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 135821-12-4
5-O-<(tert-butyl)diphenylsilyl>-2-deoxy-3,4-O-isopropylidene-aldehydo-D-ribose

Guidance literature:: Multi-step reaction with 3 steps

1: 82 percent / imidazole / dimethylformamide / 6 h / Ambient temperature

2: 81 percent / TsOH / 12 h / Ambient temperature

3: 53 percent / HgO, HgCl₂ / acetone; H₂O / 5 h / Heating

With 1H-imidazole; toluene-4-sulfonic acid; mercury dichloride; mercury(II) oxide; In water; N,N-dimethyl-formamide; acetone;
DOI:10.1002/hlca.19920750516