N-((3-(4-methoxycarbonylphenyl)bicyclo[1.1.0]but-1-yl)(phenyl)methyl)-N-(2-methylallyl)-P,P-diphenylphosphinamide

Base Information

Chemical Name:N-((3-(4-methoxycarbonylphenyl)bicyclo[1.1.0]but-1-yl)(phenyl)methyl)-N-(2-methylallyl)-P,P-diphenylphosphinamide
CAS No.:908120-56-9
Molecular Formula:C₃₅H₃₄NO₃P
Molecular Weight:547.634
Hs Code.:

Synonyms:N-((3-(4-methoxycarbonylphenyl)bicyclo[1.1.0]but-1-yl)(phenyl)methyl)-N-(2-methylallyl)-P,P-diphenylphosphinamide

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Chemical Property of N-((3-(4-methoxycarbonylphenyl)bicyclo[1.1.0]but-1-yl)(phenyl)methyl)-N-(2-methylallyl)-P,P-diphenylphosphinamide

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Technology Process of N-((3-(4-methoxycarbonylphenyl)bicyclo[1.1.0]but-1-yl)(phenyl)methyl)-N-(2-methylallyl)-P,P-diphenylphosphinamide

There total 4 articles about N-((3-(4-methoxycarbonylphenyl)bicyclo[1.1.0]but-1-yl)(phenyl)methyl)-N-(2-methylallyl)-P,P-diphenylphosphinamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 908073-38-1
N-((3-(4-methoxycarbonylphenyl)bicyclo[1.1.0]but-1-yl)(phenyl)methyl)-P,P-diphenylphosphinamide

: 1458-98-6
2-methyl-3-bromo-1-propene

: 908120-56-9
N-((3-(4-methoxycarbonylphenyl)bicyclo[1.1.0]but-1-yl)(phenyl)methyl)-N-(2-methylallyl)-P,P-diphenylphosphinamide

Guidance literature:: With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate; In toluene; at 20 ℃; for 1h;
DOI:10.1002/anie.200600723

Reference yield:

: 619-44-3
methyl 4-iodobenzoate

: 908120-56-9
N-((3-(4-methoxycarbonylphenyl)bicyclo[1.1.0]but-1-yl)(phenyl)methyl)-N-(2-methylallyl)-P,P-diphenylphosphinamide

Guidance literature:: Multi-step reaction with 3 steps

1.1: 59 percent / CuI; iPr₂NH / Pd(PPh₃)4 / tetrahydrofuran / 1.5 h / 0 °C

2.1: Me₂Zn / CH₂Cl₂; toluene / 1 h / 0 °C

2.2: 42 percent / CH₂Cl₂; toluene / 0.5 h / 0 °C

3.1: 90 percent / Bu₄NHSO₄; aq. NaOH / toluene / 1 h / 20 °C

With sodium hydroxide; copper(l) iodide; dimethyl zinc(II); tetra(n-butyl)ammonium hydrogensulfate; diisopropylamine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; dichloromethane; toluene;
DOI:10.1002/anie.200600723

Reference yield:

: 98837-46-8,67764-52-7
P,P-diphenyl-N-(phenylmethylene)phosphinic amide

: 908120-56-9
N-((3-(4-methoxycarbonylphenyl)bicyclo[1.1.0]but-1-yl)(phenyl)methyl)-N-(2-methylallyl)-P,P-diphenylphosphinamide

Guidance literature:: Multi-step reaction with 4 steps

1.1: 90 percent / tetrahydrofuran / 0.5 h / 0 °C

2.1: 59 percent / CuI; iPr₂NH / Pd(PPh₃)4 / tetrahydrofuran / 1.5 h / 0 °C

3.1: Me₂Zn / CH₂Cl₂; toluene / 1 h / 0 °C

3.2: 42 percent / CH₂Cl₂; toluene / 0.5 h / 0 °C

4.1: 90 percent / Bu₄NHSO₄; aq. NaOH / toluene / 1 h / 20 °C

With sodium hydroxide; copper(l) iodide; dimethyl zinc(II); tetra(n-butyl)ammonium hydrogensulfate; diisopropylamine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; dichloromethane; toluene;
DOI:10.1002/anie.200600723