5-(4,4'-dimethoxydiphenylamino)-2,2'-bipyridine

Base Information

• Chemical Name: 5-(4,4'-dimethoxydiphenylamino)-2,2'-bipyridine
• CAS No.: 1253521-80-0
• Molecular Formula: C₂₄H₂₁N₃O₂
• Molecular Weight: 383.45
• Mol file: 1253521-80-0.mol

Synonyms:5-(4,4'-dimethoxydiphenylamino)-2,2'-bipyridine

Chemical Property of 5-(4,4'-dimethoxydiphenylamino)-2,2'-bipyridine

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 5-(4,4'-dimethoxydiphenylamino)-2,2'-bipyridine

There total 1 articles about 5-(4,4'-dimethoxydiphenylamino)-2,2'-bipyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

5-bromo-2,2'-bipyridyl (15862-19-8) + bis(4-methoxyphenyl)amine (101-70-2) → 5-(4,4'-dimethoxydiphenylamino)-2,2'-bipyridine (1253521-80-0)

Guidance literature:

With palladium diacetate; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; In toluene; at 95 ℃; for 35h; Inert atmosphere;

DOI:10.1021/ic101471u

Reference yield: 61.0%

nickel bis(1,1,1,5,5,5-hexafluoroacetylacetonato) dihydrate + 5-(4,4'-dimethoxydiphenylamino)-2,2'-bipyridine (1253521-80-0) → [Ni(hexafluoroacetylacetonato)2(5-(4,4'-dimethoxydiphenylamino)-2,2'bipyridine)] (1253521-84-4)

Guidance literature:

In hexane; dichloromethane; (inert atm., Schlenk technique); mixing suspn. of nickel compd. in hexanes with CH2Cl2 soln. of bipyridine deriv., stirring at room temp. overnight; evapn., dissolving in hot hexanes, cooling to room temp., filtration, elem. anal.;

DOI:10.1021/ic101471u

Reference yield: 51.0%

copper(II) hexafluoroacetylacetonate hydrate + 5-(4,4'-dimethoxydiphenylamino)-2,2'-bipyridine (1253521-80-0) → [Cu(hexafluoroacetylacetonato)2(5-(4,4'-dimethoxydiphenylamino)-2,2'bipyridine)] (1253521-86-6)

Guidance literature:

In hexane; dichloromethane; (inert atm., Schlenk technique); mixing suspn. of copper compd. in hexanes/CH2Cl2 (2:1) with CH2Cl2 soln. of bipyridine deriv., stirring at roomtemp. for 3 h; evapn., dissolving in hot methanol, slow evapn., filtration, elem. anal.;

DOI:10.1021/ic101471u

upstream raw materials:

5-bromo-2,2'-bipyridyl

bis(4-methoxyphenyl)amine

Downstream raw materials:

[Ni(hexafluoroacetylacetonato)2(5-(4,4'-dimethoxydiphenylamino)-2,2'bipyridine)]

[Cu(hexafluoroacetylacetonato)2(5-(4,4'-dimethoxydiphenylamino)-2,2'bipyridine)]

[Mn(hexafluoroacetylacetonato)2(5-(4,4'-dimethoxydiphenylamino)-2,2'bipyridine)]