Technology Process of C24H32O2Si
There total 4 articles about C24H32O2Si which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
oxalyl dichloride; dimethyl sulfoxide; N-ethyl-N,N-diisopropylamine;
In
dichloromethane;
at -78 ℃;
for 0.166667h;
DOI:10.1002/chem.200700838
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: magnesium / ethylene dibromide; tetrahydrofuran / 1 h / Inert atmosphere; Reflux
1.2: 5 h / -78 °C / Inert atmosphere
2.1: 1H-imidazole / N,N-dimethyl-formamide / 20 °C / Inert atmosphere
3.1: hydrogenchloride / isopropyl alcohol; water / 2 h / 0 - 20 °C / Inert atmosphere
4.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 2 h / -78 °C / Inert atmosphere
4.2: 2 h / -78 - 20 °C / Inert atmosphere
With
1H-imidazole; hydrogenchloride; oxalyl dichloride; magnesium; dimethyl sulfoxide;
In
tetrahydrofuran; dichloromethane; water; ethylene dibromide; N,N-dimethyl-formamide; isopropyl alcohol;
4.1: |Swern Oxidation;
DOI:10.1002/asia.201403325
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: hydrogenchloride / isopropyl alcohol; water / 2 h / 0 - 20 °C / Inert atmosphere
2.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 2 h / -78 °C / Inert atmosphere
2.2: 2 h / -78 - 20 °C / Inert atmosphere
With
hydrogenchloride; oxalyl dichloride; dimethyl sulfoxide;
In
dichloromethane; water; isopropyl alcohol;
2.1: |Swern Oxidation;
DOI:10.1002/asia.201403325
