(2E,6Z)-7-benzyl-3,11-dimethyldodeca-2,6,10-trienyl diphosphate

Base Information

Chemical Name:(2E,6Z)-7-benzyl-3,11-dimethyldodeca-2,6,10-trienyl diphosphate
CAS No.:1312586-19-8
Molecular Formula:C₂₁H₃₂O₇P₂
Molecular Weight:458.428
Hs Code.:

Synonyms:(2E,6Z)-7-benzyl-3,11-dimethyldodeca-2,6,10-trienyl diphosphate

Suppliers and Price of (2E,6Z)-7-benzyl-3,11-dimethyldodeca-2,6,10-trienyl diphosphate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (2E,6Z)-7-benzyl-3,11-dimethyldodeca-2,6,10-trienyl diphosphate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (2E,6Z)-7-benzyl-3,11-dimethyldodeca-2,6,10-trienyl diphosphate

There total 8 articles about (2E,6Z)-7-benzyl-3,11-dimethyldodeca-2,6,10-trienyl diphosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₂₁H₂₉Cl

: 1312586-19-8
(2E,6Z)-7-benzyl-3,11-dimethyldodeca-2,6,10-trienyl diphosphate

Guidance literature:: With tris(tetra-n-butylammonium) hydrogen pyrophosphate; In acetonitrile; at 20 ℃; for 3h; Inert atmosphere;
DOI:10.1021/ol201069x

Reference yield:

: 1312586-06-3
(Z)-4-benzyl-8-methylnona-3,7-dien-1-ol

: 1312586-19-8
(2E,6Z)-7-benzyl-3,11-dimethyldodeca-2,6,10-trienyl diphosphate

Guidance literature:: Multi-step reaction with 5 steps

1.1: 1H-imidazole; iodine; triphenylphosphine / dichloromethane / 0 - 20 °C / Inert atmosphere

2.1: tert.-butyl lithium; zinc dibromide / tetrahydrofuran / -78 - 20 °C / Inert atmosphere

2.2: 18 h / 20 °C / Inert atmosphere

3.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 0 - 20 °C / Inert atmosphere

4.1: N-chloro-succinimide; dimethylsulfide / dichloromethane / -30 - 0 °C / Inert atmosphere

5.1: tris(tetra-n-butylammonium) hydrogen pyrophosphate / acetonitrile / 3 h / 20 °C / Inert atmosphere

With 1H-imidazole; N-chloro-succinimide; dimethylsulfide; tetrabutyl ammonium fluoride; iodine; tert.-butyl lithium; tris(tetra-n-butylammonium) hydrogen pyrophosphate; triphenylphosphine; zinc dibromide; In tetrahydrofuran; dichloromethane; acetonitrile; 4.1: Corey-Kim chlorination;
DOI:10.1021/ol201069x

Reference yield:

: 1312586-09-6
(Z)-(2-(3-iodopropylidene)-6-methylhept-5-enyl)benzene

: 1312586-19-8
(2E,6Z)-7-benzyl-3,11-dimethyldodeca-2,6,10-trienyl diphosphate

Guidance literature:: Multi-step reaction with 4 steps

1.1: tert.-butyl lithium; zinc dibromide / tetrahydrofuran / -78 - 20 °C / Inert atmosphere

1.2: 18 h / 20 °C / Inert atmosphere

2.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 0 - 20 °C / Inert atmosphere

3.1: N-chloro-succinimide; dimethylsulfide / dichloromethane / -30 - 0 °C / Inert atmosphere

4.1: tris(tetra-n-butylammonium) hydrogen pyrophosphate / acetonitrile / 3 h / 20 °C / Inert atmosphere

With N-chloro-succinimide; dimethylsulfide; tetrabutyl ammonium fluoride; tert.-butyl lithium; tris(tetra-n-butylammonium) hydrogen pyrophosphate; zinc dibromide; In tetrahydrofuran; dichloromethane; acetonitrile; 3.1: Corey-Kim chlorination;
DOI:10.1021/ol201069x