(7R,9R)-11-(4-Methoxy-benzyloxy)-7-methoxymethoxy-9-methyl-undec-1-en-6-one

Base Information

Chemical Name:(7R,9R)-11-(4-Methoxy-benzyloxy)-7-methoxymethoxy-9-methyl-undec-1-en-6-one
CAS No.:900149-65-7
Molecular Formula:C₂₂H₃₄O₅
Molecular Weight:378.509
Hs Code.:

Synonyms:(7R,9R)-11-(4-Methoxy-benzyloxy)-7-methoxymethoxy-9-methyl-undec-1-en-6-one

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Chemical Property of (7R,9R)-11-(4-Methoxy-benzyloxy)-7-methoxymethoxy-9-methyl-undec-1-en-6-one

Chemical Property:

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Technology Process of (7R,9R)-11-(4-Methoxy-benzyloxy)-7-methoxymethoxy-9-methyl-undec-1-en-6-one

There total 13 articles about (7R,9R)-11-(4-Methoxy-benzyloxy)-7-methoxymethoxy-9-methyl-undec-1-en-6-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 934705-30-3
(7R,9R)-11-(4-Methoxy-benzyloxy)-7-methoxymethoxy-9-methyl-undec-1-en-6-ol

: 900149-65-7
(7R,9R)-11-(4-Methoxy-benzyloxy)-7-methoxymethoxy-9-methyl-undec-1-en-6-one

Guidance literature:: With pyridine; Dess-Martin periodane; In dichloromethane;
DOI:10.1016/j.tet.2006.03.066

Reference yield:

: (S)-6-(4-methoxybenzyloxy)-4-methylhexanal

: 900149-65-7
(7R,9R)-11-(4-Methoxy-benzyloxy)-7-methoxymethoxy-9-methyl-undec-1-en-6-one

Guidance literature:: Multi-step reaction with 9 steps

1.1: 9.95 g / 2-methyl-2-butene; NaH₂PO₄; sodium chlorite / 2-methyl-propan-2-ol; H₂O

2.1: triethylamine / tetrahydrofuran / -78 - 20 °C

3.1: 15.5 g / n-BuLi / tetrahydrofuran / -78 - 0 °C

4.1: sodium hexamethyldisilazide / tetrahydrofuran / 0.5 h / -78 °C

4.2: 76 percent / Davis reagent / tetrahydrofuran / 0.17 h

5.1: 67 percent / diisopropylethylamine / CH₂Cl₂ / 0 °C

6.1: 81 percent / LiBH₄ / tetrahydrofuran; H₂O / 2 h / 0 °C

7.1: 91 percent / oxalyl chloride; DMSO; triethylamine / CH₂Cl₂ / -78 - 0 °C

8.1: Mg; iodine / diethyl ether / 1 h

8.2: 85 percent / diethyl ether / -78 - 0 °C

9.1: 86 percent / pyridine; Dess-Martin periodinane / CH₂Cl₂

With pyridine; sodium chlorite; sodium dihydrogenphosphate; lithium borohydride; n-butyllithium; 2-methyl-but-2-ene; oxalyl dichloride; iodine; sodium hexamethyldisilazane; Dess-Martin periodane; magnesium; dimethyl sulfoxide; triethylamine; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; diethyl ether; dichloromethane; water; tert-butyl alcohol; 7.1: Swern oxidation;
DOI:10.1016/j.tet.2006.03.066

Reference yield:

: 934704-86-6
(S)-4-methoxybenzyl 3,7-dimethyl-6-octenyl ether

: 900149-65-7
(7R,9R)-11-(4-Methoxy-benzyloxy)-7-methoxymethoxy-9-methyl-undec-1-en-6-one

Guidance literature:: Multi-step reaction with 11 steps

1.1: NMO; OsO₄ / 2-methyl-propan-2-ol; tetrahydrofuran; H₂O / 19 h

2.1: sodium periodate / tetrahydrofuran; 2-methyl-propan-2-ol; H₂O / 1.5 h

3.1: 9.95 g / 2-methyl-2-butene; NaH₂PO₄; sodium chlorite / 2-methyl-propan-2-ol; H₂O

4.1: triethylamine / tetrahydrofuran / -78 - 20 °C

5.1: 15.5 g / n-BuLi / tetrahydrofuran / -78 - 0 °C

6.1: sodium hexamethyldisilazide / tetrahydrofuran / 0.5 h / -78 °C

6.2: 76 percent / Davis reagent / tetrahydrofuran / 0.17 h

7.1: 67 percent / diisopropylethylamine / CH₂Cl₂ / 0 °C

8.1: 81 percent / LiBH₄ / tetrahydrofuran; H₂O / 2 h / 0 °C

9.1: 91 percent / oxalyl chloride; DMSO; triethylamine / CH₂Cl₂ / -78 - 0 °C

10.1: Mg; iodine / diethyl ether / 1 h

10.2: 85 percent / diethyl ether / -78 - 0 °C

11.1: 86 percent / pyridine; Dess-Martin periodinane / CH₂Cl₂

With pyridine; sodium chlorite; sodium periodate; sodium dihydrogenphosphate; osmium(VIII) oxide; lithium borohydride; n-butyllithium; N-methyl-2-indolinone; 2-methyl-but-2-ene; oxalyl dichloride; iodine; sodium hexamethyldisilazane; Dess-Martin periodane; magnesium; dimethyl sulfoxide; triethylamine; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; diethyl ether; dichloromethane; water; tert-butyl alcohol; 9.1: Swern oxidation;
DOI:10.1016/j.tet.2006.03.066