(3S,5Z,8S,9R)-2-methylene-3-(trimethylsilanyloxy)-8-(tert-butyldiphenylsilanyloxy)-9-vinyl-2,3,4,7,8,9-hexahydrooxonine

Base Information

Chemical Name:(3S,5Z,8S,9R)-2-methylene-3-(trimethylsilanyloxy)-8-(tert-butyldiphenylsilanyloxy)-9-vinyl-2,3,4,7,8,9-hexahydrooxonine
CAS No.:1172121-68-4
Molecular Formula:C₃₀H₄₂O₃Si₂
Molecular Weight:506.833
Hs Code.:

Synonyms:(3S,5Z,8S,9R)-2-methylene-3-(trimethylsilanyloxy)-8-(tert-butyldiphenylsilanyloxy)-9-vinyl-2,3,4,7,8,9-hexahydrooxonine

Suppliers and Price of (3S,5Z,8S,9R)-2-methylene-3-(trimethylsilanyloxy)-8-(tert-butyldiphenylsilanyloxy)-9-vinyl-2,3,4,7,8,9-hexahydrooxonine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (3S,5Z,8S,9R)-2-methylene-3-(trimethylsilanyloxy)-8-(tert-butyldiphenylsilanyloxy)-9-vinyl-2,3,4,7,8,9-hexahydrooxonine

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (3S,5Z,8S,9R)-2-methylene-3-(trimethylsilanyloxy)-8-(tert-butyldiphenylsilanyloxy)-9-vinyl-2,3,4,7,8,9-hexahydrooxonine

There total 1 articles about (3S,5Z,8S,9R)-2-methylene-3-(trimethylsilanyloxy)-8-(tert-butyldiphenylsilanyloxy)-9-vinyl-2,3,4,7,8,9-hexahydrooxonine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: Tebbe's reagent

: 1172121-71-9
(3S,5Z,8S,9R)-3-(trimethylsilanyloxy)-8-(tert-butyldiphenylsilanyloxy)-9-vinyl-2,3,4,7,8,9-hexahydrooxonin-2(7H)-one

: C₃₁H₄₆O₃Si₂

: 1172121-68-4
(3S,5Z,8S,9R)-2-methylene-3-(trimethylsilanyloxy)-8-(tert-butyldiphenylsilanyloxy)-9-vinyl-2,3,4,7,8,9-hexahydrooxonine

Guidance literature:: With dmap; In tetrahydrofuran; toluene; at -45 - 20 ℃; for 2h; Inert atmosphere;
DOI:10.1016/j.tetasy.2009.03.010

Reference yield: 76.0%

: 1172121-68-4
(3S,5Z,8S,9R)-2-methylene-3-(trimethylsilanyloxy)-8-(tert-butyldiphenylsilanyloxy)-9-vinyl-2,3,4,7,8,9-hexahydrooxonine

: 1172121-69-5
(3S,5Z,8S,9R)-2-methylene-3-hydroxy-8-(tert-butyldiphenylsilanyloxy)-9-vinyl-2,3,4,7,8,9-hexahydrooxonine

Guidance literature:: (3S,5Z,8S,9R)-2-methylene-3-(trimethylsilanyloxy)-8-(tert-butyldiphenylsilanyloxy)-9-vinyl-2,3,4,7,8,9-hexahydrooxonine; With tetrabutyl ammonium fluoride; In tetrahydrofuran; at -10 ℃; for 0.25h; Inert atmosphere;

With water; sodium hydrogencarbonate; In tetrahydrofuran; diethyl ether;
DOI:10.1016/j.tetasy.2009.03.010