Carbonic acid;copper

Base Information

• Chemical Name: Carbonic acid;copper
• CAS No.: 1184-64-1
• Molecular Formula: CHO₃*Cu
• Molecular Weight: 124.563
• Mol file: 1184-64-1.mol

Synonyms:CuCO3

Chemical Property of Carbonic acid;copper

Chemical Property:

• Appearance/Colour: green or blue powder
• Vapor Pressure: 2.58E-05mmHg at 25°C
• Melting Point: 200 °C
• Boiling Point: decomposes at 290 °C
• Flash Point: 169.8 °C
• PSA: 63.19000
• Density: 3.9 g/cm³
• LogP: -2.44950
• Storage Temp.: Inert atmosphere,Room Temperature
• Water Solubility.: insoluble H2O
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 124.929991
• Heavy Atom Count: 5
• Complexity: 29.9

Purity/Quality:

99.9% ^*data from raw suppliers

Cupriccarbonate 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=O)(O)O.[Cu]
• Description: Copper(II) carbonate?or?cupric carbonate?is a?chemical compound?with formula?CuCO3. At ambient temperatures, it is an?ionic solid?(a?salt) consisting of?copper(II)?cations?Cu2+and?carbonate?anions?CO32? .
• Uses: Copper(I) carbonate is known as cuprous carbonate since copper’s ion is +1; copper(II) carbonate (Cu2+ + CO3 2- → CuCO3) is known as cupric carbonate, which is also known as the green copper mineral malachite, used in pigments, as an insecticide, as a cosmetic astringent, and as a plant fungicide to prevent smut.

Refernces

Effect of hydrogen bonding on the coordination: Part 2. Semi-coordination in trans-di(salicylato)bis(1,3-diaminopropane-N,N')copper(II)

10.1016/S0020-1693(01)00605-3

The research aimed to investigate the impact of hydrogen bonding on coordination, particularly semi-coordination, in transition metal complexes, using trans-di(salicylato)bis(1,3-diaminopropane-N,N’)copper(II) as a model compound. The study employed single-crystal X-ray diffraction methods at 193(2) K to determine the crystal and molecular structure of the complex. The central copper(II) ion was found to occupy a center of symmetry within a monomeric complex unit, with the coordination polyhedron described as an axially elongated distorted octahedron, indicative of semi-coordination. The research concluded that semi-coordination is characterized by electrostatic attraction between the central copper(II) cation and repulsion between an electron lone pair of a ligand atom and the electron lone pair at the copper(II) 3dz2 atomic orbital. The chemicals used in the synthesis of the complex included salicylic acid, CuCO3, and 1,3-diaminopropane, with the final product being characterized by various analytical methods.