3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-propanal

Base Information

Chemical Name:3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-propanal
CAS No.:96056-11-0
Molecular Formula:C₁₉H₂₆O₄
Molecular Weight:318.413
Hs Code.:

Synonyms:3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-propanal

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Chemical Property of 3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-propanal

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Technology Process of 3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-propanal

There total 3 articles about 3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-propanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 96056-23-4
3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-propan-1-ol

: 96056-11-0
3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-propanal

Guidance literature:: With oxalyl dichloride; triethylamine; In dichloromethane; dimethyl sulfoxide; for 0.25h;
DOI:10.1021/ja00297a037

Reference yield:

: 96149-11-0
methyl 3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-cis-propenoate

: 96056-11-0
3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-propanal

Guidance literature:: Multi-step reaction with 3 steps

1: 94 percent / H₂ / Rh/C (5percent) / pentane / 5 h / Ambient temperature

2: 100 percent / LAH / diethyl ether / 1 h / 0 °C

3: 97 percent / (COCl)2, Et₃N / CH₂Cl₂; dimethylsulfoxide / 0.25 h

With lithium aluminium tetrahydride; oxalyl dichloride; hydrogen; triethylamine; Rh on carbon; In diethyl ether; dichloromethane; dimethyl sulfoxide; pentane;
DOI:10.1021/ja00297a037

Reference yield:

: 96056-22-3
methyl 3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-propanoate

: 96056-11-0
3-<(5R,4S,6R)-4,6-dimethyl-7(S)-(benzyloxy)-2,9-dioxabicyclo<3.3.1>nonan-1-yl>-propanal

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / LAH / diethyl ether / 1 h / 0 °C

2: 97 percent / (COCl)2, Et₃N / CH₂Cl₂; dimethylsulfoxide / 0.25 h

With lithium aluminium tetrahydride; oxalyl dichloride; triethylamine; In diethyl ether; dichloromethane; dimethyl sulfoxide;
DOI:10.1021/ja00297a037