3-O-benzoyl-6-O-tert-butyldiphenylsilyl-5-deoxy-5-iodo-1,2-O-isopropylidene-β-L-idofuranose

Base Information

Chemical Name:3-O-benzoyl-6-O-tert-butyldiphenylsilyl-5-deoxy-5-iodo-1,2-O-isopropylidene-β-L-idofuranose
CAS No.:188249-33-4
Molecular Formula:C₃₂H₃₇IO₆Si
Molecular Weight:672.632
Hs Code.:

Synonyms:3-O-benzoyl-6-O-tert-butyldiphenylsilyl-5-deoxy-5-iodo-1,2-O-isopropylidene-β-L-idofuranose

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Chemical Property of 3-O-benzoyl-6-O-tert-butyldiphenylsilyl-5-deoxy-5-iodo-1,2-O-isopropylidene-β-L-idofuranose

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Technology Process of 3-O-benzoyl-6-O-tert-butyldiphenylsilyl-5-deoxy-5-iodo-1,2-O-isopropylidene-β-L-idofuranose

There total 1 articles about 3-O-benzoyl-6-O-tert-butyldiphenylsilyl-5-deoxy-5-iodo-1,2-O-isopropylidene-β-L-idofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.8%

: 3-O-benzoyl-6-O-tert-butyldiphenylsilyl-1,2-O-isopropylidene-α-D-glucofuranose

: 188249-33-4
3-O-benzoyl-6-O-tert-butyldiphenylsilyl-5-deoxy-5-iodo-1,2-O-isopropylidene-β-L-idofuranose

Guidance literature:: With 1H-imidazole; iodine; triphenylphosphine; In xylene; at 80 - 140 ℃; for 26.5h;
DOI:10.1080/07328309708006509

Reference yield: 78.3%

: 188249-33-4
3-O-benzoyl-6-O-tert-butyldiphenylsilyl-5-deoxy-5-iodo-1,2-O-isopropylidene-β-L-idofuranose

: 188249-09-4
6-O-tert-butyldiphenylsilyl-5-deoxy-5-iodo-1,2-O-isopropylidene-β-L-idofuranose

Guidance literature:: With methanol; sodium methylate; at 20 ℃; for 4h;
DOI:10.1080/07328309708006509

Reference yield:

: 188249-33-4
3-O-benzoyl-6-O-tert-butyldiphenylsilyl-5-deoxy-5-iodo-1,2-O-isopropylidene-β-L-idofuranose

: (3aR,6R,6aR)-5-[2-(tert-Butyl-diphenyl-silanyloxy)-eth-(Z)-ylidene]-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol

Guidance literature:: Multi-step reaction with 2 steps

1: 78.3 percent / sodium methoxide; methanol / 4 h / 20 °C

2: sodium azide / dimethylformamide / 5 h / 90 °C

With methanol; sodium azide; sodium methylate; In N,N-dimethyl-formamide; 1: debenzoylation / 2: Substitution;
DOI:10.1080/07328309708006509