Phosphonium, benzyltributyl-, chloride

Base Information

• Chemical Name: Phosphonium, benzyltributyl-, chloride
• CAS No.: 1224-56-2
• Molecular Formula: C19H34 P . Cl
• Molecular Weight: 328.906
• Hs Code.: 2931900090
• NSC Number: 64110
• DSSTox Substance ID: DTXSID80924154
• Mol file: 1224-56-2.mol

Synonyms:1224-56-2;benzyl(tributyl)phosphonium chloride;Phosphonium, benzyltributyl-, chloride;benzyltributylphosphonium chloride;Benzyltri-N-butylphosphonium chloride;NSC 64110;benzyl(tributyl)phosphanium;chloride;Phosphonium, tributyl(phenylmethyl)-, chloride;Phosphonium, tributyl(phenylmethyl)-, chloride (1:1);benzyl(tributyl)phosphanium chloride;C19H34P.Cl;SCHEMBL465040;benzyltributylphosphoniumchloride;benyltributylphosphonium chloride;C19-H34-P.Cl;DTXSID80924154;NSC64110;benzyl (tributyl)phosphonium chloride;MFCD00775362;NSC-64110;BENZYL(TRIBUTYL)PHOSPHONIUMCHLORIDE;LS-106874;WLN: 4P4&4&1R &G &2/11

Chemical Property of Phosphonium, benzyltributyl-, chloride

Chemical Property:

• Melting Point: 164oC
• PSA: 13.59000
• LogP: 3.60850
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 11
• Exact Mass: 328.2086658
• Heavy Atom Count: 21
• Complexity: 196

Purity/Quality:

99% ^*data from raw suppliers

BENZYL(TRIBUTYL)PHOSPHONIUM CHLORIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Phosphorus Compounds
• Canonical SMILES: CCCC[P+](CCCC)(CCCC)CC1=CC=CC=C1.[Cl-]

Technology Process of Phosphonium, benzyltributyl-, chloride

There total 6 articles about Phosphonium, benzyltributyl-, chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

tributylphosphine (998-40-3) + benzyltrimethylammonium chloride (56-93-9) → tributylbenzylphosphonium chloride (1224-56-2)

Guidance literature:

at 100 ℃; for 0.166667h; Irradiation;

DOI:10.1139/v04-103

Reference yield: 94.0%

benzylmagnesium chloride (6921-34-2) + tri-n-butylchlorophosphonium chloride → tributylbenzylphosphonium chloride (1224-56-2)

Guidance literature:

In dichloromethane; at -83 ℃; Temperature;

DOI:10.1080/10426507.2018.1541242

Reference yield: 87.0%

tributylphosphine (998-40-3) + benzyl chloride (100-44-7) → tributylbenzylphosphonium chloride (1224-56-2)

Guidance literature:

In toluene; Heating;

DOI:10.1016/S0040-4020(99)00611-0

upstream raw materials:

tributylphosphine

benzyl chloride

benzyltrimethylammonium chloride

benzylmagnesium chloride

Downstream raw materials:

benzyl chloride

{(C₄H₉)3PCH₂C₆H₅}⁽¹⁺⁾*{FeCl₄}^(1-)={(C₄H₉)3PCH₂C₆H₅}{FeCl₄}

4-benzylpyrimidine

(6R)-6-transstyryl-tetrahydro-2H-pyran-2-one

Refernces

• 1、 Vetter, Anna C.,Nikitin, Kirill,Gilheany, Declan G.. "Exploring an Umpolung strategy for quaternization of phosphorus". . p. 339 - 342. Retrieved 2019/03/07.
• 2、 Schaffarczyk McHale, Karin S.,Hawker, Rebecca R.,Harper, Jason B.. "Nitrogen: Versus phosphorus nucleophiles-how changing the nucleophilic heteroatom affects ionic liquid solvent effects in bimolecular nucleophilic substitution processes". supporting information. p. 7437 - 7444. Retrieved 2016/09/12.