C₂₇H₃₆O₇

Base Information

Chemical Name:C₂₇H₃₆O₇
CAS No.:512783-16-3
Molecular Formula:C₂₇H₃₆O₇
Molecular Weight:472.579
Hs Code.:

C<sub>27</sub>H<sub>36</sub>O<sub>7</sub>

Synonyms:C₂₇H₃₆O₇

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Chemical Property of C₂₇H₃₆O₇

Chemical Property:

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Technology Process of C₂₇H₃₆O₇

There total 14 articles about C₂₇H₃₆O₇ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 512783-10-7
C₂₇H₃₆O₆

: 512783-16-3
C₂₇H₃₆O₇

Guidance literature:: C₂₇H₃₆O₆; With 18-crown-6 ether; oxygen; potassium hexamethylsilazane; In tetrahydrofuran; toluene; at -78 - 0 ℃;

With dimethylsulfide; In tetrahydrofuran; toluene; at 20 ℃; for 1h;
DOI:10.1021/jo020627v

Reference yield:

: 64180-78-5
4-bromopent-4-en-1-ol

: 512783-16-3
C₂₇H₃₆O₇

Guidance literature:: Multi-step reaction with 12 steps

1.1: 15.74 g / Et₃N; DBU / CH₂Cl₂

2.1: tert-butyllithium / tetrahydrofuran; pentane / 0.5 h / -78 °C

2.2: 99 percent / tetrahydrofuran; pentane / 3 h / -78 °C

3.1: sodium hexamethyldisilazide / tetrahydrofuran / 0.33 h / 0 °C

3.2: 88 percent / tetrahydrofuran / -78 - -30 °C

4.1: tert-butyllithium / diethyl ether; pentane / 0.03 h / -78 °C

4.2: 96 percent / diethyl ether; pentane / 3.5 h / -78 - 0 °C

5.1: potassium hexamethyldisilazide; 18-crown-6 / tetrahydrofuran; toluene / 1.48 h / -78 - -40 °C

5.2: 81 percent / tetrahydrofuran; toluene / 3 h / -78 °C

6.1: 54 percent / NMO*H₂O; osmium tetraoxide; water / acetone / 120 h / 0 °C

7.1: pyridine / CH₂Cl₂; toluene / 0.25 h / -78 °C

8.1: 890 mg / methanol; Dowex 50X₄-400 / 2.5 h

9.1: 98 percent / oxalyl chloride; DMSO; Et₃N / CH₂Cl₂ / 2.33 h / -78 - 20 °C

10.1: 12 percent / aq. sodium hydroxide / methanol; tetrahydrofuran

11.1: 78 percent / DDQ; 4 Angstroem molecular sieves / diethyl ether / 6 h / 20 °C

12.1: potassium hexamethyldisilazide; 18-crown-6; oxygen / tetrahydrofuran; toluene / -78 - 0 °C

12.2: 89 percent / dimethyl sulfide / tetrahydrofuran; toluene / 1 h / 20 °C

With pyridine; methanol; sodium hydroxide; osmium(VIII) oxide; oxalyl dichloride; 18-crown-6 ether; 4 A molecular sieve; Dowex 50X₄-400; water; tert.-butyl lithium; oxygen; sodium hexamethyldisilazane; potassium hexamethylsilazane; dimethyl sulfoxide; 4-methylmorpholine N-oxide; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; acetone; toluene; pentane; 3.2: Wittig condensation / 9.1: Swern oxidation;
DOI:10.1021/jo020627v

Reference yield:

: 120001-35-6
((4-bromopent-4-en-1-yl)oxy)(tert-butyl)dimethylsilane

: 512783-16-3
C₂₇H₃₆O₇

Guidance literature:: Multi-step reaction with 11 steps

1.1: tert-butyllithium / tetrahydrofuran; pentane / 0.5 h / -78 °C

1.2: 99 percent / tetrahydrofuran; pentane / 3 h / -78 °C

2.1: sodium hexamethyldisilazide / tetrahydrofuran / 0.33 h / 0 °C

2.2: 88 percent / tetrahydrofuran / -78 - -30 °C

3.1: tert-butyllithium / diethyl ether; pentane / 0.03 h / -78 °C

3.2: 96 percent / diethyl ether; pentane / 3.5 h / -78 - 0 °C

4.1: potassium hexamethyldisilazide; 18-crown-6 / tetrahydrofuran; toluene / 1.48 h / -78 - -40 °C

4.2: 81 percent / tetrahydrofuran; toluene / 3 h / -78 °C

5.1: 54 percent / NMO*H₂O; osmium tetraoxide; water / acetone / 120 h / 0 °C

6.1: pyridine / CH₂Cl₂; toluene / 0.25 h / -78 °C

7.1: 890 mg / methanol; Dowex 50X₄-400 / 2.5 h

8.1: 98 percent / oxalyl chloride; DMSO; Et₃N / CH₂Cl₂ / 2.33 h / -78 - 20 °C

9.1: 12 percent / aq. sodium hydroxide / methanol; tetrahydrofuran

10.1: 78 percent / DDQ; 4 Angstroem molecular sieves / diethyl ether / 6 h / 20 °C

11.1: potassium hexamethyldisilazide; 18-crown-6; oxygen / tetrahydrofuran; toluene / -78 - 0 °C

11.2: 89 percent / dimethyl sulfide / tetrahydrofuran; toluene / 1 h / 20 °C

With pyridine; methanol; sodium hydroxide; osmium(VIII) oxide; oxalyl dichloride; 18-crown-6 ether; 4 A molecular sieve; Dowex 50X₄-400; water; tert.-butyl lithium; oxygen; sodium hexamethyldisilazane; potassium hexamethylsilazane; dimethyl sulfoxide; 4-methylmorpholine N-oxide; triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; acetone; toluene; pentane; 2.2: Wittig condensation / 8.1: Swern oxidation;
DOI:10.1021/jo020627v