(2Z,4S,5R,6E,8S,9R,10S,12S,13R)-1,5-bis(tert-butyldimethylsilyloxy)-13-<3'-(2'',5''-dimethylpyrrol-1''-yl)-2',5'-dimethoxyphenyl>-9,10,13-trimethoxy-4,6,8,12-tetramethyl-2,6-tridecadiene

Base Information Edit

Chemical Name:(2Z,4S,5R,6E,8S,9R,10S,12S,13R)-1,5-bis(tert-butyldimethylsilyloxy)-13-<3'-(2'',5''-dimethylpyrrol-1''-yl)-2',5'-dimethoxyphenyl>-9,10,13-trimethoxy-4,6,8,12-tetramethyl-2,6-tridecadiene
CAS No.:175356-65-7
Molecular Formula:C₄₆H₈₁NO₇Si₂
Molecular Weight:816.323
Hs Code.:
Mol file:175356-65-7.mol

(2Z,4S,5R,6E,8S,9R,10S,12S,13R)-1,5-bis(tert-butyldimethylsilyloxy)-13-<3'-(2'',5''-dimethylpyrrol-1''-yl)-2',5'-dimethoxyphenyl>-9,10,13-trimethoxy-4,6,8,12-tetramethyl-2,6-tridecadiene

Synonyms:(2Z,4S,5R,6E,8S,9R,10S,12S,13R)-1,5-bis(tert-butyldimethylsilyloxy)-13-<3'-(2'',5''-dimethylpyrrol-1''-yl)-2',5'-dimethoxyphenyl>-9,10,13-trimethoxy-4,6,8,12-tetramethyl-2,6-tridecadiene

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Chemical Property of (2Z,4S,5R,6E,8S,9R,10S,12S,13R)-1,5-bis(tert-butyldimethylsilyloxy)-13-<3'-(2'',5''-dimethylpyrrol-1''-yl)-2',5'-dimethoxyphenyl>-9,10,13-trimethoxy-4,6,8,12-tetramethyl-2,6-tridecadiene Edit

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Technology Process of (2Z,4S,5R,6E,8S,9R,10S,12S,13R)-1,5-bis(tert-butyldimethylsilyloxy)-13-<3'-(2'',5''-dimethylpyrrol-1''-yl)-2',5'-dimethoxyphenyl>-9,10,13-trimethoxy-4,6,8,12-tetramethyl-2,6-tridecadiene

There total 3 articles about (2Z,4S,5R,6E,8S,9R,10S,12S,13R)-1,5-bis(tert-butyldimethylsilyloxy)-13-<3'-(2'',5''-dimethylpyrrol-1''-yl)-2',5'-dimethoxyphenyl>-9,10,13-trimethoxy-4,6,8,12-tetramethyl-2,6-tridecadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 175356-64-6
(2Z,4S,5R,6E,8S,9R,10S,12S,13R)-13-<3'-(2'',5''-dimethylpyrrol-1''-yl)-2',5'-dimethoxyphenyl>-9,10,13-trimethoxy-4,6,8,12-tetramethyl-2,6-tridecadien-1,5-diol

: 133732-91-9
tert-butyldimethylsilyl triflate

: 175356-65-7
(2Z,4S,5R,6E,8S,9R,10S,12S,13R)-1,5-bis(tert-butyldimethylsilyloxy)-13-<3'-(2'',5''-dimethylpyrrol-1''-yl)-2',5'-dimethoxyphenyl>-9,10,13-trimethoxy-4,6,8,12-tetramethyl-2,6-tridecadiene

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at -20 ℃; for 0.5h;
DOI:10.1016/0040-4020(95)01107-2

Reference yield:

: 175356-63-5
(2Z,4S,5R,6E,8S,9R,10S,12S,13R)-1-tert-butyldiphenylsilyloxy-13-<3'-(2'',5''-dimethyl-pyrrol-1''-yl)-2',5'-dimethoxyphenyl>-5-triisopropylsilyloxy-9,10,13-trimethoxy-4,6,8,12-tetramethyl-2,6-tridecadiene

: 175356-65-7
(2Z,4S,5R,6E,8S,9R,10S,12S,13R)-1,5-bis(tert-butyldimethylsilyloxy)-13-<3'-(2'',5''-dimethylpyrrol-1''-yl)-2',5'-dimethoxyphenyl>-9,10,13-trimethoxy-4,6,8,12-tetramethyl-2,6-tridecadiene

Guidance literature:: Multi-step reaction with 2 steps

1: 98 percent / TBAF / tetrahydrofuran / 2 h / Ambient temperature

2: 99 percent / 2,6-lutidine / CH₂Cl₂ / 0.5 h / -20 °C

With 2,6-dimethylpyridine; tetrabutyl ammonium fluoride; In tetrahydrofuran; dichloromethane;
DOI:10.1016/0040-4020(95)01107-2