5-(4-chloro-phenyliminomethyleneamino)-1-phenyl-1H-[1,2,3]triazole-4-carboxylic acid ethyl ester

Base Information

• Chemical Name: 5-(4-chloro-phenyliminomethyleneamino)-1-phenyl-1H-[1,2,3]triazole-4-carboxylic acid ethyl ester
• CAS No.: 863786-32-7
• Molecular Formula: C₁₈H₁₄ClN₅O₂
• Molecular Weight: 367.794

Synonyms:5-(4-chloro-phenyliminomethyleneamino)-1-phenyl-1H-[1,2,3]triazole-4-carboxylic acid ethyl ester

Chemical Property of 5-(4-chloro-phenyliminomethyleneamino)-1-phenyl-1H-[1,2,3]triazole-4-carboxylic acid ethyl ester

Chemical Property:

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Technology Process of 5-(4-chloro-phenyliminomethyleneamino)-1-phenyl-1H-[1,2,3]triazole-4-carboxylic acid ethyl ester

There total 2 articles about 5-(4-chloro-phenyliminomethyleneamino)-1-phenyl-1H-[1,2,3]triazole-4-carboxylic acid ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

p-chlorphenylisocyanate (104-12-1) + 1-Phenyl-5-(triphenylphosphoranylidenamino)-1,2,3-triazol-4-carbonsaeure-ethylester (90543-08-1) → 5-(4-chloro-phenyliminomethyleneamino)-1-phenyl-1H-[1,2,3]triazole-4-carboxylic acid ethyl ester (863786-32-7)

Guidance literature:

DOI:10.1246/cl.2005.1022

Reference yield:

ethyl 5-amino-1-phenyl-1,2,3-triazole-4-carboxylate (20271-37-8) → 5-(4-chloro-phenyliminomethyleneamino)-1-phenyl-1H-[1,2,3]triazole-4-carboxylic acid ethyl ester (863786-32-7)

Guidance literature:

Multi-step reaction with 2 steps

1: triethylamine / hexachloroethane; acetonitrile / 3 h / 20 °C

2: dichloromethane / 20 °C / Inert atmosphere

With triethylamine; In dichloromethane; hexachloroethane; acetonitrile; 2: Aza-Wittig reaction;

DOI:10.1080/10426507.2011.590169

Reference yield: 96.0%

5-(4-chloro-phenyliminomethyleneamino)-1-phenyl-1H-[1,2,3]triazole-4-carboxylic acid ethyl ester (863786-32-7) + 4-Fluorothiophenol (371-42-6) → 6-(4-chlorophenyl)-3,6-dihydro-5-[(p-fluorophenyl)thio]-3-phenyl-1,2,3-triazolo-[4,5-d]pyrimidine-7-one (1356190-26-5)

Guidance literature:

With sodium ethanolate; potassium carbonate; In acetonitrile; at 50 ℃;

DOI:10.1080/10426507.2011.590169

upstream raw materials:

p-chlorphenylisocyanate

1-Phenyl-5-(triphenylphosphoranylidenamino)-1,2,3-triazol-4-carbonsaeure-ethylester

ethyl 5-amino-1-phenyl-1,2,3-triazole-4-carboxylate

Downstream raw materials:

5-[N'-(4-chloro-phenyl)-N''-isopropyl-guanidino]-1-phenyl-1H-[1,2,3]triazole-4-carboxylic acid ethyl ester

6-amino-5-(4-chlorophenyl)amino-3,6-dihydro-3-phenyl-7H-1,2,3-triazolo[4,5-d]pyrimidin-7-one

5-(4-chlorophenyl)amino-3,6-dihydro-3-phenyl-6-(triphenylphosphoranylidene)amino-7H-1,2,3-triazolo[4,5-d]pyrimidin-7-one

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