Styelolide

Base Information

• Chemical Name: Styelolide
• CAS No.: 80375-67-3
• Molecular Formula: C₂₂H₃₂O₅
• Molecular Weight: 376.493
• Mol file: 80375-67-3.mol

Synonyms:Styelolide;Cyclotetradeca(b)furan-2(3H)-one, 5-(acetyloxy)-3a,4,5,6,7,8,11,12,15,15a-decahydro-6-hydroxy-6,10,14-trimethyl-3-methylene-, (3aS-(3aR*,5R*,6S*,9Z,13Z,15aR*))-;80375-67-3;NSC 301688

Chemical Property of Styelolide

Chemical Property:

• Vapor Pressure: 6.78E-13mmHg at 25°C
• Boiling Point: 518°C at 760 mmHg
• Flash Point: 172.9°C
• Density: 1.1g/cm³
• XLogP3: 3.2
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 2
• Exact Mass: 376.22497412
• Heavy Atom Count: 27
• Complexity: 660

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CCCC(C(CC2C(CC(=CCC1)C)OC(=O)C2=C)OC(=O)C)(C)O
• Isomeric SMILES: C/C/1=C/CCC(C(CC2C(C/C(=C/CC1)/C)OC(=O)C2=C)OC(=O)C)(C)O

Technology Process of Styelolide

There total 1 articles about Styelolide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Acetic acid (9E,13E)-(3S,3aS,5S,6R,15aS)-6-hydroxy-6,10,14-trimethyl-2-oxo-3-phenylsulfanylmethyl-2,3,3a,4,5,6,7,8,11,12,15,15a-dodecahydro-1-oxa-cyclopentacyclotetradecen-5-yl ester (80375-71-9) → Acetic acid (9E,13E)-(3aS,5S,6R,15aS)-6-hydroxy-6,10,14-trimethyl-3-methylene-2-oxo-2,3,3a,4,5,6,7,8,11,12,15,15a-dodecahydro-1-oxa-cyclopentacyclotetradecen-5-yl ester (80375-67-3)

Guidance literature:

With pyridine; sodium periodate; Yield given. Multistep reaction; 1.) CH₃OH, benzene, 0 deg C, 2.) toluene, reflux, 4 h;

DOI:10.1021/jo00343a019

upstream raw materials:

Acetic acid (9E,13E)-(3S,3aS,5S,6R,15aS)-6-hydroxy-6,10,14-trimethyl-2-oxo-3-phenylsulfanylmethyl-2,3,3a,4,5,6,7,8,11,12,15,15a-dodecahydro-1-oxa-cyclopentacyclotetradecen-5-yl ester